[Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2]

Base Information

• Chemical Name: [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2]
• CAS No.: 155111-16-3
• Molecular Formula: C₂₈H₂₄F₁₀Ir₂S₂
• Molecular Weight: 999.055
• Mol file: 155111-16-3.mol

Synonyms:

Chemical Property of [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2]

There total 1 articles about [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

(1,5-cyclooctadiene)(methoxy)iridium(I) dimer + pentafluorophenylthiol (771-62-0) → [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2] (155111-16-3)

Guidance literature:

In dichloromethane; (Ar); a stirred soln. of Ir-complex in CH2Cl2 at room temp. treated withC6F5SH; hexane added after 20 min; concentrated; powder washed with hexane; elem. anal.;

DOI:10.1016/j.poly.2008.03.001

Reference yield: 53.0%

[Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2] (155111-16-3) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) + HSiPh3 (789-25-3) → [Ir(SC6F5)(H)(SiPh3)(2,6-dimethylphenylisocyanide)3](benzene)

Guidance literature:

In benzene; (Ar); a stirred mixture of Ir-complex and Ph3SiH in benzene treated withxylyl isocyanide; concd.; hexane added; crystals obtained after 3 d at -20°C; washed with hexane; elem. anal.;

DOI:10.1016/j.poly.2008.03.001

Reference yield: 4.0%

hexane (110-54-3) + [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2] (155111-16-3) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Ir3(μ-SC6F5)2(SC6F5)(μ,μ'-2,6-dimethylphenylisocyanide)(2,6-dimethylphenylisocyanide)4(1,5-cyclooctadiene)](n-hexane)

Guidance literature:

In dichloromethane; (Ar); mixture of Ir-complex and xylyl isocyanide dissolved in CH2Cl2; soln. treated with hexane, concentrated and allowed to stand at -20°C for 6 d; crystals separated; powder contained unidentified products;

DOI:10.1016/j.poly.2008.03.001

upstream raw materials:

pentafluorophenylthiol