(2-bp)Au(N(COMe)C₆H₄NH(COMe))Cl

Base Information

• Chemical Name: (2-bp)Au(N(COMe)C₆H₄NH(COMe))Cl
• CAS No.: 928171-64-6
• Molecular Formula: C₂₂H₂₁AuClN₃O₂
• Molecular Weight: 591.847
• Mol file: 928171-64-6.mol

Synonyms:

Chemical Property of (2-bp)Au(N(COMe)C₆H₄NH(COMe))Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-bp)Au(N(COMe)C₆H₄NH(COMe))Cl

There total 3 articles about (2-bp)Au(N(COMe)C₆H₄NH(COMe))Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2-bp)Au(N(COMe)C6H4N(COMe)) (928171-51-1) + sodium chloride (7647-14-5) → (2-bp)Au(N(COMe)C6H4NH(COMe))Cl (928171-64-6)

Guidance literature:

With benzoic acid; In methanol; dichloromethane; 1 equiv. of NaCl in MeOH was added to CH2Cl2-soln. of Au-complex, 1 equiv. of benzoic acid was added; soln. was filtered, concd., Et2O was added; identified by (1)H NMR;

DOI:10.1016/j.poly.2006.06.036

Reference yield:

[gold(III)(dichloro)(2-benzylpyridine)] (171509-49-2) + N,N'-(o-phenylene)di(acetamide) (2050-85-3) → (2-bp)Au(N(COMe)C6H4NH(COMe))Cl (928171-64-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Ag₂O / dichloromethane

2: chloroform-d1

With Ag₂O; In chloroform-d1; dichloromethane;

DOI:10.1016/j.poly.2006.06.036

Reference yield:

[gold(III)(dichloro)(2-benzylpyridine)] (171509-49-2) + N,N'-(o-phenylene)di(acetamide) (2050-85-3) → (2-bp)Au(N(COMe)C6H4N(COMe)) (928171-51-1) + (2-bp)Au(N(COMe)C6H4NH(COMe))Cl (928171-64-6)

Guidance literature:

With Ag₂O; H₂O; In dichloromethane; 1-1 equiv. of Au-compd. and acetamido-compd. were added to CH2Cl2 together with excess of Ag2O, reflux for 2 h; soln. was filtered, evapd. in vac., residue was redissolved in CH2Cl2, filtered through alumina, slow addn. of Et2O, crystals were filtered off,washed with Et2O and twice with H2O, dried in vac., elem. anal.;

DOI:10.1016/j.poly.2006.06.036

upstream raw materials:

(2-bp)Au(N(COMe)C₆H₄N(COMe))

sodium chloride

[gold(III)(dichloro)(2-benzylpyridine)]

N,N'-(o-phenylene)di(acetamide)