rhamnolipid

Base Information

• Chemical Name: rhamnolipid
• CAS No.: 125135-03-7
• Molecular Formula: C₃₂H₅₈O₁₃
• Molecular Weight: 650.805
• Mol file: 125135-03-7.mol

Synonyms:

Chemical Property of rhamnolipid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of rhamnolipid

There total 21 articles about rhamnolipid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(R)-3-{(R)-3-[2-O-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl]oxydecanoyl}oxy-(R)-decanoic acid (202824-37-1) → rhamnolipid (125135-03-7,122911-24-4)

Guidance literature:

With hydrogen; palladium on activated charcoal; In water; acetic acid; isopropyl alcohol; for 48h;

DOI:10.1002/(sici)1099-0690(199802)1998:2<303::aid-ejoc303>3.0.co;2-u

Reference yield: 75.0%

C67H88O13 → rhamnolipid (125135-03-7,122911-24-4)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; acetic acid; In ethanol; for 24h; under 7500.75 Torr; Autoclave;

DOI:10.1016/j.carres.2020.108102

Reference yield:

ethyl 2,3,4-tri-O-benzyl-1-thio-α-L-rhamanopyranoside (128962-63-0,116391-11-8) → rhamnolipid (125135-03-7,122911-24-4)

Guidance literature:

Multi-step reaction with 7 steps

1: N-iodosuccinimide, triflic acid

2: N-iodosuccinimide, triflic acid

3: 96 percent / Zn/AcOH / 1.5 h / 20 °C

4: 73 percent / DCC, DMAP / CH₂Cl₂ / 18 h

5: 96 percent / Zn/AcOH / 1.5 h / 20 °C

6: 87 percent / acetic acid, water / 2 h / 100 °C

7: 92 percent / H₂ / 10percent Pd/C / propan-2-ol; H₂O; acetic acid / 48 h

With dmap; N-iodo-succinimide; trifluorormethanesulfonic acid; water; hydrogen; acetic acid; dicyclohexyl-carbodiimide; zinc; palladium on activated charcoal; In dichloromethane; water; acetic acid; isopropyl alcohol;

DOI:10.1002/(sici)1099-0690(199802)1998:2<303::aid-ejoc303>3.0.co;2-u

upstream raw materials:

D-Fructose

glycerol

(R)-3-{(R)-3-[2-O-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl]oxydecanoyl}oxy-(R)-decanoic acid

ethyl 2,3,4-tri-O-benzyl-1-thio-α-L-rhamanopyranoside