Technology Process of Ir(CO)I(P(C6H5)3)2(O2C6H3CH2CH2NH2)
There total 1 articles about Ir(CO)I(P(C6H5)3)2(O2C6H3CH2CH2NH2) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium hydroxide;
In
methanol; benzene;
benzene soln. of ligand was added to MeOH soln. of KOH, this mixt. was syringed to Ir-complex in benzene, mixt. was stirred in the dark at roomtemp. for 20 h; concd. at reduced pressure, filtered, washed with benzene, H2O, dissolved in CH2Cl2, dried over MgSO4, filtered through alumina column, solventwas removed at reduced pressure, ppt. was washed with hexane, dried in vac.; elem. anal.;
DOI:10.1016/S0020-1693(00)87308-9
- Guidance literature:
-
With
triethylamine;
In
tetrahydrofuran;
THF soln. contg. ligand and Et3N was syringed to Ir-complex in THF at 0°C, soln. was stirred for 20 min at 0°C, then for 1 h at room temp.; solvent was removed at reduced pressure, washed with H2O, dried in vac., dissolved in CH2Cl2, chromd. on silica gel with CH2Cl2 contg. MeOH, eluate was evapd. to dryness, washed with petroleum ether; elem. anal.;
DOI:10.1016/S0020-1693(00)87308-9
