Technology Process of Digermane, 1,2-dimethyl-1,1,2,2-tetraphenyl-
There total 13 articles about Digermane, 1,2-dimethyl-1,1,2,2-tetraphenyl- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
(Ar); soln. of SmI2 (2 equiv.) in THF was added to soln. of MePh2GeBr inhexamethylphosphoric triamide; mixt. was stirred at room temp. for 1 h; chromd. (silica gel, ether); evapd.; chromd. (silica gel, hexane);
DOI:10.1016/j.jorganchem.2004.12.032
- Guidance literature:
-
With
PPh3;
In
benzene-d6;
heating in a sealed tube at 120°C for 5 h in the presence of 5 mol equiv. of PPh3; monitored by NMR;
DOI:10.1246/bcsj.74.123
- Guidance literature:
-
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
(Ar); soln. of SmI2 (2 equiv.) in THF was added to soln. of MePh2GeCl inhexamethylphosphoric triamide; mixt. was stirred at room temp. for 12 h; chromd. (silica gel, ether); evapd.; chromd. (silica gel, hexane);
DOI:10.1016/j.jorganchem.2004.12.032
