Germane, chloromethyldiphenyl-

Base Information

• Chemical Name: Germane, chloromethyldiphenyl-
• CAS No.: 115514-17-5
• Molecular Formula: C13H13ClGe
• Molecular Weight: 277.289
• Mol file: 115514-17-5.mol

Synonyms:

Chemical Property of Germane, chloromethyldiphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Germane, chloromethyldiphenyl-

There total 5 articles about Germane, chloromethyldiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

chlorine (7782-50-5) + methyldiphenylgermane (2870-92-0) → methyldiphenylgermanium chloride (115514-17-5)

Guidance literature:

In tetrachloromethane; Irradiation (UV/VIS); bubbling Cl2 gas through the solution, gas source removing, irradiation (sunlamp, 8 min); solvent removing (vac. distillation);

DOI:10.1021/ja973756f

Reference yield: 95.0%

1,2-dimethyl-1,1,2,2-tetraphenylgermane (13892-12-1) → methyldiphenylgermanium chloride (115514-17-5)

Guidance literature:

With tetrachloromethane; In cyclohexane; Irradiation (UV/VIS); dissolution of digermane and CCl4 as trapping agent in dry cyclohexane in a quartz tube, degassing in a vacuum, charging with argon, irradiation with a 110 W low pressure Hg arc lamp at room temp. for 2 h; verrifying the photoproducts by GLC and GC-MS;

DOI:10.1246/bcsj.64.1889

Reference yield: 95.0%

tetrachloromethane (56-23-5) + 1,2-dimethyl-1,1,2,2-tetraphenylgermane (13892-12-1) → methyldiphenylgermanium chloride (115514-17-5)

Guidance literature:

In cyclohexane; for 0.333333h; Product distribution; Mechanism; Ambient temperature; Irradiation; further digermenes;

DOI:10.1246/bcsj.64.1889

upstream raw materials:

tetrachloromethane

1,2-dimethyl-1,1,2,2-tetraphenylgermane

chlorine

methyldiphenylgermane

Downstream raw materials:

Li⁽¹⁺⁾*Ge(C₆H₅)2(CH₃)^(1-)=Ge(C₆H₅)2(CH₃)Li

methoxymethyldiphenylgermane

1,2-dimethyl-1,1,2,2-tetraphenylgermane

(C₆H₂(CH₃)3)3GeGe(CH₃)(C₆H₅)2

Refernces

• 1、 Mochida, Kunio,Wakasa, Masanobu,Sakaguchi, Yoshio,Hayashi, Hisaharu. "Photochemical Reactions of Aryl-Substituted Digermanes through a Pair of Organogermyl Radicals". . p. 1889 - 1895. Retrieved 1991.
• 2、 Mochida, Kunio,Wakasa, Masanobu,Nakadaira, Yasuhiro,Sakaguchi, Yoshio,Hayashi, Hisaharu. "Laser photolysis of aryl-substituted digermanes. Generation of germyl radicals and germylenes". . p. 1869 - 1871. Retrieved 2008/10/08.