α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran

Base Information

• Chemical Name: α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran
• CAS No.: 51848-95-4
• Molecular Formula: C₃₀H₃₃O₂PS
• Molecular Weight: 488.631
• Mol file: 51848-95-4.mol

Synonyms:

Chemical Property of α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran

There total 4 articles about α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Adamantanecarboxylic acid (828-51-3) → α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran (51848-95-4)

Guidance literature:

Multi-step reaction with 4 steps

1: LiAlH₄ / diethyl ether / Heating

2: H₃PO₄, P₂O₅, NaI

4: (i) nBuLi, (ii) /BRN= 972316/

With lithium aluminium tetrahydride; phosphoric acid; phosphorus pentoxide; sodium iodide; In diethyl ether;

DOI:10.1021/jo00932a013

Reference yield:

1-adamantanemethanol (770-71-8) → α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran (51848-95-4)

Guidance literature:

Multi-step reaction with 3 steps

1: H₃PO₄, P₂O₅, NaI

3: (i) nBuLi, (ii) /BRN= 972316/

With phosphoric acid; phosphorus pentoxide; sodium iodide;

DOI:10.1021/jo00932a013

Reference yield:

1-adamantane methyl iodide (51849-10-6) → α-1-Adamantylmethylsulfonyl-methylidentriphenylphosphoran (51848-95-4)

Guidance literature:

Multi-step reaction with 2 steps

2: (i) nBuLi, (ii) /BRN= 972316/

DOI:10.1021/jo00932a013

upstream raw materials:

Methanesulfonic anhydride

1-adamantanemethanol

1-Adamantanecarboxylic acid

1-adamantane methyl iodide