[(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane

Base Information

Chemical Name:[(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane
CAS No.:1262336-59-3
Molecular Formula:C₂₃H₃₈F₆NO₆S₂SbSi
Molecular Weight:752.516
Hs Code.:

Synonyms:

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Chemical Property of [(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane

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Technology Process of [(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane

There total 1 articles about [(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1262336-58-2
dichloro[(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]stibane

: 2923-28-6
silver trifluoromethanesulfonate

: 1262336-59-3
[(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane

Guidance literature:: In dichloromethane; byproducts: AgCl; Schlenk techniques used under Ar, 2,4,6-tri-tBu-phenyl-N(SiMe3)SbCl2 added to stirred suspn. of AgOTf in CH2Cl2 at -80 °C, warmed up to 0°C for 30 min; concentrated, crystallizated at -25 °C; XRD;
DOI:10.1002/ejic.201000885

Reference yield: 94.0%

: 1262336-59-3
[(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane

: 869482-79-1
1,3-ditriflate-2,4-bis(2,4,6-tri-tertbutylphenyl)-cyclo-1,3-distiba-2,4-diazane

Guidance literature:: In dichloromethane; byproducts: Me3SiOTf; Schlenk techniques used under Ar, soln. of 2,4,6-tri-tBu-phenyl-N(SiMe3)Sb(OTf)2 in CH2Cl2 warmed at 35 °C for 36 h; concentrated, crystallizated at -25 °C for several h; XRD;
DOI:10.1002/ejic.201000885

Reference yield: 85.0%

: 4648-54-8
trimethylsilylazide

: 1262336-59-3
[(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)amino]bis(trifluoromethylsulfonyl)stibane

: 1367179-62-1
(N₃)(OTf)Sb(SiMe₃)(2,4,6-tri-tert-butylphenyl)

Guidance literature:: In dichloromethane; under oxygen- and moisture-free condns.; using Schlenk and glovebox techniques; Me3SiN3 in CH2Cl2 added at -60°C to stirred soln. of Sb compd. in CH2Cl2; warmed to room temp. over 20 min; solvent removed in vac., residue recrystd. from hexane; solvent removed,dried; elem. anal.;
DOI:10.1002/ejic.201101107