[Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

Base Information

Chemical Name:[Re(hydride)(nitrosyl)2(triisopropylphosphine)2]
CAS No.:219815-97-1
Molecular Formula:C₁₈H₄₃N₂O₂P₂Re
Molecular Weight:567.706
Hs Code.:

Synonyms:

Suppliers and Price of [Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

There total 3 articles about [Re(hydride)(nitrosyl)2(triisopropylphosphine)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.7%

: 617-86-7
triethylsilane

: 234077-86-2
[Re2(hydride)(μ,η2-nitrosyl)(nitrosyl)3(triisopropylphosphine)4][B(3,5-(CF3)2C6H3)4]

: 219815-97-1
[Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

: [Re(hydride)(nitrosyl)(triisopropylphosphine)2(NOSi(CH₂CH₃)3)][B(3,5-(CF₃)2C₆H₃)4]

Guidance literature:: In chlorobenzene; under N2; the complex was dissolved in C6H5Cl, HSi(CH2CH3)3 was added; after 1 d crystals were collected, washed with pentane, dried under vac.;
DOI:10.1021/om010409c

Reference yield: 77.2%

: 234077-86-2
[Re2(hydride)(μ,η2-nitrosyl)(nitrosyl)3(triisopropylphosphine)4][B(3,5-(CF3)2C6H3)4]

: 75-05-8,26809-02-9
acetonitrile

: 219815-97-1
[Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

: 389613-58-5
[Re(nitrosyl)2(triisopropylphosphine)2(CH₃CN)][B(3,5-(CF₃)2C₆H₃)4]

Guidance literature:: In benzene; under N2; Re complex was dissolved in C6H6 and treated with an excess ofCH3CN; the soln. was dried under vac., the residue was washed with pentane, thesolid was recrystd. from C6H5Cl/pentane, the crystals were washed with pentane and dried in vac.;
DOI:10.1021/om010409c

Reference yield: 68.5%

: 234077-86-2
[Re2(hydride)(μ,η2-nitrosyl)(nitrosyl)3(triisopropylphosphine)4][B(3,5-(CF3)2C6H3)4]

: 201230-82-2
carbon monoxide

: 219815-97-1
[Re(hydride)(nitrosyl)2(triisopropylphosphine)2]

: 389613-64-3
[Re(nitrosyl)2(triisopropylphosphine)2(carbonyl)][B(3,5-(CF₃)2C₆H₃)4]

Guidance literature:: In benzene; under N2; the complex was placed in a flask with a Teflon valve, C6H6 was added, the mixt. was placed under 1 atm of CO and shaken until all thestarting material dissolved; the solvent was removed under vac., the residue was washed with pentane,the solid was recrystd. from C6H5Cl/pentane, after 24 h brown crystals were collected, washed with pentane, dried in vac.;
DOI:10.1021/om010409c