(2,6-iPr₂C₆H₃N(SiMe₃)AlI₂)2

Base Information

• Chemical Name: (2,6-iPr₂C₆H₃N(SiMe₃)AlI₂)2
• CAS No.: 607356-27-4
• Molecular Formula: C₃₀H₅₂Al₂I₄N₂Si₂
• Molecular Weight: 1058.51
• Mol file: 607356-27-4.mol

Synonyms:

Chemical Property of (2,6-iPr₂C₆H₃N(SiMe₃)AlI₂)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (2,6-iPr₂C₆H₃N(SiMe₃)AlI₂)2

There total 1 articles about (2,6-iPr₂C₆H₃N(SiMe₃)AlI₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(2,6-i-Pr2C6H3)N(SiMe3)AlMe2 + iodine (7553-56-2,12190-71-5,8031-47-8) → (2,6-iPr2C6H3N(SiMe3)AlI2)2 (607356-27-4)

Guidance literature:

In toluene; I2 in toluene was slowly added to toluene soln. of Al-complex at -78°C, stirred for 2 h, slowly warmed to room temp., stirred overnight in the dark; volatiles were removed under vac., cold pentane was added, filtered, pentane was removed; elem. anal.;

DOI:10.1021/om0302793

Reference yield: 32.0%

di-isopropyl ether (108-20-3) + (2,6-iPr2C6H3N(SiMe3)AlI2)2 (607356-27-4) → (2,6-iPr2C6H3N(SiMe3)Al)4*diisopropyl ether

Guidance literature:

With Na/K alloy; In hexane; Al-complex in hexane was treated with Na/K alloy, stirred for 12 d at room temp.; filtered, hexane was removed, treated with dimethoxyethane, filtered, solvent was removed under vac., iPr2O was added, stored for 3 d at 12°C; elem. anal.;

DOI:10.1021/om0302793

upstream raw materials:

iodine