Technology Process of [Ni(C20H6N4(C6H4CH3)3(C6H3(CH3)NH)CHO)]
There total 2 articles about [Ni(C20H6N4(C6H4CH3)3(C6H3(CH3)NH)CHO)] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: acetic acid; acetic anhydride / chloroform; acetic acid
2: triethyl phosphite / further solvent(s)
3: phosphorus oxychloride / dichloromethane; N,N-dimethyl-formamide
With
acetic acid; acetic anhydride; triethyl phosphite; phosphorus oxychloride;
In
dichloromethane; chloroform; acetic acid; N,N-dimethyl-formamide;
DOI:10.1021/ic035203d
- Guidance literature:
-
Multi-step reaction with 2 steps
1: triethyl phosphite / further solvent(s)
2: phosphorus oxychloride / dichloromethane; N,N-dimethyl-formamide
With
triethyl phosphite; phosphorus oxychloride;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ic035203d
- Guidance literature:
-
In
1,2-dichloro-ethane;
under Ar; soln. of Pd acetate in 1,2-dichloroethane added dropwise to soln. of nickel enaminoaldehyde in 1,2-dichloroethane at 60°C; reaction stopped after 30-40% conversion (monitored by TLC); rapid evapn., rapid chromy. (silica gel, CCl4/CH2Cl2 (4/1) to (1/1));
DOI:10.1021/ic035203d
