Palladium(2+);hexaacetate

Base Information

• Chemical Name: Palladium(2+);hexaacetate
• CAS No.: 53189-26-7
• Molecular Formula: C12H18 O12 Pd3
• Molecular Weight: 673.528
• Hs Code.: 2915290000
• European Community (EC) Number: 258-424-9
• Mol file: 53189-26-7.mol

Synonyms:palladium(2+);hexaacetate;53189-26-7;Hexakis(acetate)tripalladium(II);palladium(ii) acetate trimer;palladium (ii) acetate trimer;Tripalladium(II) Hexaacetate;Hexakis(acetato)tripalladium(II);P2106

Chemical Property of Palladium(2+);hexaacetate

Chemical Property:

• PSA: 157.80000
• LogP: 0.08280
• Solubility.: soluble in Acetone
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 672.79228
• Heavy Atom Count: 27
• Complexity: 25.5

Purity/Quality:

97% ^*data from raw suppliers

Palladium(II) Acetate Trimer ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Pd+2].[Pd+2].[Pd+2]

Technology Process of Palladium(2+);hexaacetate

There total 7 articles about Palladium(2+);hexaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

palladium (II) nitrate + acetic acid (64-19-7,77671-22-8) + ethyl acetate (141-78-6) → palladium(II) acetate trimer (53189-26-7)

Guidance literature:

In water; soln. of Pd salt heated to 80-90°C, soln. of ethyl acetate added for 30 min in several portions at 70-90°C; N2 passed through soln.; then glacial CH3COOH added, heated to 100°C, then heated to 120-140°C for 30 min, cooled; crystd. at 15-25°C, ppt. filtered off, washed (water, glacial CH3COOH), dried in air or in a drying box at temp. not exceeding 150°C; elem. anal., detd. by XRD, DTA;

DOI:10.1134/S1070427210120013

Reference yield: 94.4%

palladium (7440-05-3) + acetic acid (64-19-7,77671-22-8) → palladium(II) acetate trimer (53189-26-7)

Guidance literature:

With HNO₃; In acetic acid; byproducts: NO2, H2O; activated Pd suspended in glacial acetic acid, concd. HNO3 added slowly,refluxed for 30 min under N2; concd., cooled to room temp., filtered;

DOI:10.1039/b502122g

Reference yield: 94.0%

acetic acid (64-19-7,77671-22-8) + palladium dichloride → palladium acetate (53189-26-7)

Guidance literature:

palladium dichloride; With sodium formate; sodium hydroxide; In water; for 0.5h;

acetic acid; With nitric acid; at 118 ℃; for 1h; Inert atmosphere;

upstream raw materials:

acetic acid

palladium

ethyl acetate

palladium pivalate

Downstream raw materials:

diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II)

palladium(II) iodide

tetrakis(triphenylphosphine) palladium⁽⁰⁾