C₂₃H₃₄O₃Si

Base Information

• Chemical Name: C₂₃H₃₄O₃Si
• CAS No.: 1369677-28-0
• Molecular Formula: C₂₃H₃₄O₃Si
• Molecular Weight: 386.607
• Mol file: 1369677-28-0.mol

Synonyms:

Chemical Property of C₂₃H₃₄O₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₃₄O₃Si

There total 6 articles about C₂₃H₃₄O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal (91751-24-5,92817-88-4,123284-89-9,112897-04-8) → C23H34O3Si (1369677-28-0)

Guidance literature:

Multi-step reaction with 4 steps

1: benzene / 80 °C

2: diisobutylaluminium hydride / diethyl ether

3: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate

4: copper(l) iodide

With titanium(IV) isopropylate; tert.-butylhydroperoxide; copper(l) iodide; diethyl (2S,3S)-tartrate; diisobutylaluminium hydride; In diethyl ether; benzene;

DOI:10.1016/j.tetlet.2012.02.049

Reference yield:

ethyl (4S)-5-(((tert-butyldiphenyl)silyl)oxy)-4-methyl-2(E)-pentenoate (133604-03-2) → C23H34O3Si (1369677-28-0)

Guidance literature:

Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / diethyl ether

2: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate

3: copper(l) iodide

With titanium(IV) isopropylate; tert.-butylhydroperoxide; copper(l) iodide; diethyl (2S,3S)-tartrate; diisobutylaluminium hydride; In diethyl ether;

DOI:10.1016/j.tetlet.2012.02.049

Reference yield:

(R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate (95514-03-7) → C23H34O3Si (1369677-28-0)

Guidance literature:

Multi-step reaction with 6 steps

1: diisobutylaluminium hydride / dichloromethane

2: oxalyl dichloride; dimethyl sulfoxide; triethylamine

3: benzene / 80 °C

4: diisobutylaluminium hydride / diethyl ether

5: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate

6: copper(l) iodide

With titanium(IV) isopropylate; tert.-butylhydroperoxide; copper(l) iodide; oxalyl dichloride; diethyl (2S,3S)-tartrate; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; In diethyl ether; dichloromethane; benzene;

DOI:10.1016/j.tetlet.2012.02.049

upstream raw materials:

methyllithium

((2R,3R)-3-((R)-1-((tert-butyldiphenylsilyl)oxy)propan-2-yl)oxiran-2-yl)methanol

(4S)-5-(tert-butyldiphenylsilyloxy)-4-methyl-2-penten-1-ol

(R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal