Tris[2-(propan-2-yl)phenyl]phosphane

Base Information

Chemical Name:Tris[2-(propan-2-yl)phenyl]phosphane
CAS No.:139026-11-2
Molecular Formula:C27H33P
Molecular Weight:388.533
Hs Code.:
DSSTox Substance ID:DTXSID80514276
Nikkaji Number:J2.150.263D
Wikidata:Q82374498
Mol file:139026-11-2.mol

Synonyms:Tris[2-(propan-2-yl)phenyl]phosphane;139026-11-2;SCHEMBL3769639;DTXSID80514276

Suppliers and Price of Tris[2-(propan-2-yl)phenyl]phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Tris[2-(propan-2-yl)phenyl]phosphane

Chemical Property:

Boiling Point:472.7±44.0 °C(Predicted)
PSA：13.59000
LogP:6.81500
XLogP3:8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:388.231988050
Heavy Atom Count:28
Complexity:387

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C1=CC=CC=C1P(C2=CC=CC=C2C(C)C)C3=CC=CC=C3C(C)C

Technology Process of Tris[2-(propan-2-yl)phenyl]phosphane

There total 2 articles about Tris[2-(propan-2-yl)phenyl]phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 7073-94-1
1-bromo-2-isopropylbenzene

: 139026-11-2
tri(o-isopropylphenyl)phosphine

Guidance literature:: 1-bromo-2-isopropylbenzene; With magnesium; ethylene dibromide; In tetrahydrofuran; for 2h; Heating;

With phosphorus trichloride; In tetrahydrofuran; at 20 - 50 ℃; for 4h;
DOI:10.1039/b610123b

Reference yield:

: 643-28-7
2-isopropylaniline

: 139026-11-2
tri(o-isopropylphenyl)phosphine

Guidance literature:: Multi-step reaction with 2 steps

1.1: aq. HBr / 0.5 h / Heating

1.2: aq. NaNO₂ / 0 - 5 °C

1.3: 60 percent / CuBr; aq. HBr / 1 h / Heating

2.1: magnesium; 1,2-dibromoethane / tetrahydrofuran / 2 h / Heating

2.2: 59 percent / PCl₃ / tetrahydrofuran / 4 h / 20 - 50 °C

With hydrogen bromide; magnesium; ethylene dibromide; In tetrahydrofuran;
DOI:10.1039/b610123b

Reference yield: 51.0%

: 139026-11-2
tri(o-isopropylphenyl)phosphine

: 41884-65-5,60479-35-8,51014-04-1
dichlorobis(trimethylacetonitrile)platinum(II)

: 849191-92-0
trans-[PtCl₂(tri-o-isopropylphenylphosphine)2]

: 849355-05-1
trans-[Pt₂Cl₂(tri-o-isopropylphenylphosphine-H)2]

Guidance literature:: In toluene; under N2; ligand (0.458 mmol) and Pt-contg. compd. (0.231 mmol) were dissolved in toluene, heated at reflux for 50 h and cooled to room temp.; the soln. was filtered; the solid was washed with cold toluene and then dried in vac.; elem. anal.;
DOI:10.1039/b416525j