PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2H⁽¹⁺⁾*CF₃SO₃^(1-)=PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2HCF₃SO₃

Base Information

• Chemical Name: PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2H⁽¹⁺⁾*CF₃SO₃^(1-)=PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2HCF₃SO₃
• CAS No.: 447408-52-8
• Molecular Formula: CF₃O₃S*C₄₅H₄₈P₃Pd
• Molecular Weight: 937.288

Synonyms:

Chemical Property of PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2H⁽¹⁺⁾*CF₃SO₃^(1-)=PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2HCF₃SO₃

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Technology Process of PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2H⁽¹⁺⁾*CF₃SO₃^(1-)=PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2HCF₃SO₃

There total 2 articles about PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2H⁽¹⁺⁾*CF₃SO₃^(1-)=PdCH₃(C₆H₅)2PCHCHP(C₆H₅)2P((CH₃)3C₆H₂)2HCF₃SO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

PdCH3Cl(C6H5)2PCHCHP(C6H5)2 (447408-63-1) + dimesityl phosphine (1732-66-7) + silver trifluoromethanesulfonate (2923-28-6) → PdCH3(C6H5)2PCHCHP(C6H5)2P((CH3)3C6H2)2H(1+)*CF3SO3(1-)=PdCH3(C6H5)2PCHCHP(C6H5)2P((CH3)3C6H2)2HCF3SO3 (447408-52-8)

Guidance literature:

In tetrahydrofuran; acetonitrile; AgOTf and ligand were added to Pd-complex in THF/MeCN, allowed to stand for 15 min under N2 at 20°C; filtered, solvent was removed under vac., washed with petroleum ether, dried in vacuo; elem. anal.;

DOI:10.1021/om020249k

Reference yield:

cis-1,2-bis-(diphenylphosphino)ethene (983-80-2) → PdCH3(C6H5)2PCHCHP(C6H5)2P((CH3)3C6H2)2H(1+)*CF3SO3(1-)=PdCH3(C6H5)2PCHCHP(C6H5)2P((CH3)3C6H2)2HCF3SO3 (447408-52-8)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: tetrahydrofuran; acetonitrile

In tetrahydrofuran; toluene; acetonitrile;

DOI:10.1021/om020249k

Reference yield: 63.0%

PdCH3(C6H5)2PCHCHP(C6H5)2P((CH3)3C6H2)2H(1+)*CF3SO3(1-)=PdCH3(C6H5)2PCHCHP(C6H5)2P((CH3)3C6H2)2HCF3SO3 (447408-52-8) → Pd(C6H5)2PCHCHP(C6H5)2(CH2C6H2(CH3)2P(CH3)3C6H2)H(1+)*CF3SO3(1-)=Pd(C6H5)2PCHCHP(C6H5)2CH2C6H2(CH3)2P(CH3)3C6H2HCF3SO3 (447408-57-3)

Guidance literature:

In tetrahydrofuran; byproducts: CH4; Pd-complex in THF was placed in NMR tube, heated at 60-65°C for 3ds under N2; filtered, petroleum ether was added, cooled to -30°C; elem. anal.;

DOI:10.1021/om020249k

upstream raw materials:

PdCH₃Cl(C₆H₅)2PCHCHP(C₆H₅)2

dimesityl phosphine

silver trifluoromethanesulfonate

cis-1,2-bis-(diphenylphosphino)ethene

Downstream raw materials:

Pd(C₆H₅)2PCHCHP(C₆H₅)2(CH₂C₆H₂(CH₃)2P(CH₃)3C₆H₂)H⁽¹⁺⁾*CF₃SO₃^(1-)=Pd(C₆H₅)2PCHCHP(C₆H₅)2CH₂C₆H₂(CH₃)2P(CH₃)3C₆H₂HCF₃SO₃

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