bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate

Base Information

• Chemical Name: bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate
• CAS No.: 935742-17-9
• Molecular Formula: C₄₂H₄₁N₂NiP₂S₂*ClO₄*H₂O
• Molecular Weight: 876.036
• Mol file: 935742-17-9.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate

There total 2 articles about bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

ammonium perchlorate (7790-98-9) + nickel(II) chloride hexahydrate + bis(4-methylpiperazinecarbodithioato) nickel(II) + triphenylphosphine (603-35-0) → bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate (935742-17-9)

Guidance literature:

In methanol; dichloromethane; Ni-complex, PPh3, NiCl2*6H2O and NH4ClO4 refluxed for .apprx.2 h in CH3OH/CH2Cl2 1:1 mixt.; concd.; filtered; kept for evapn.; filtered; dried; recrystallized from CH3OH/CH2Cl2 1:1 mixt.; elem. anal.;

DOI:10.1016/j.poly.2006.10.006

Reference yield:

1-methyl-piperazine (109-01-3) → bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate (935742-17-9)

Guidance literature:

Multi-step reaction with 2 steps

1: water; ethanol

2: dichloromethane; methanol

In methanol; ethanol; dichloromethane; water;

DOI:10.1016/j.poly.2006.10.006

upstream raw materials:

ammonium perchlorate

triphenylphosphine

1-methyl-piperazine

Refernces