(C₁₂H₆N₂(CHNC₉H₆N)2)2Cu₃⁽³⁺⁾

Base Information

• Chemical Name: (C₁₂H₆N₂(CHNC₉H₆N)2)2Cu₃⁽³⁺⁾
• CAS No.: 899795-23-4
• Molecular Formula: C₆₄H₄₀Cu₃N₁₂
• Molecular Weight: 1167.74
• Mol file: 899795-23-4.mol

Synonyms:

Chemical Property of (C₁₂H₆N₂(CHNC₉H₆N)2)2Cu₃⁽³⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₁₂H₆N₂(CHNC₉H₆N)2)2Cu₃⁽³⁺⁾

There total 6 articles about (C₁₂H₆N₂(CHNC₉H₆N)2)2Cu₃⁽³⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyridine-2-carbaldehyde (1121-60-4) + 8-amino quinoline (578-66-5) + tetrakis(acetonitrile)copper(I)tetrafluoroborate + 1,10-phenanthroline-2,9-dicarboxaldehyde (57709-62-3) + p-toluidine (106-49-0,12221-03-3) → [Cu((4-methylphenyl)pyridin-2-ylmethylene-amine)2](1+) (181063-25-2) + 2(C5H3N(CHNC9H6N)(CHNC6H4CH3))*2Cu(1+)=((C5H3N(CHNC9H6N)(CHNC6H4CH3)))2Cu2(2+) + (C12H6N2(CHNC9H6N)2)2Cu3(3+) (899795-23-4)

Guidance literature:

With C₅H₃N(CHO)2; In dimethylsulfoxide-d6; [D₃]acetonitrile; in capped NMR tube C7H7(NH2), C9H9N(NH2), C5H4N(CHO), C12H6N2(CHO)2, C5H3N(CHO)2, Cu(CH3CN)4(BF4) (4+6:2+2+2:6) (CD3CN), (Ar); kept at room temp., at 50°C for 50 h; volume reduced (vac.); ppt. dissolution (DMSO-D6), kept at 50°C for 24 h; monitored by (1)HNMR over 7 d;

DOI:10.1002/anie.200703877

Reference yield:

8-amino quinoline (578-66-5) + tetrakis(acetonitrile)copper(I)tetrafluoroborate + 1,10-phenanthroline-2,9-dicarboxaldehyde (57709-62-3) + p-toluidine (106-49-0,12221-03-3) → (C12H6N2(CHNC6H4CH3)2)2Cu2(2+) (908240-22-2) + (C12H6N2(CHNC9H6N)2)2Cu3(3+) (899795-23-4)

Guidance literature:

In dimethylsulfoxide-d6; [D₃]acetonitrile; in capped NMR tube C7H7(NH2), C9H6N(NH2), C12H6N2(CHO)2, Cu(CH3CN)4(BF4)(4+4:4:5) (CD3CN), purged (Ar); kept overnight at room temp., at 50.deg ree.C for 50 h;volume of solvent reduced under vac.; ppt. dissolution inDMSO-D6, kept at 50°C for 24h; monitored by (1)HNMR over 7 d;

DOI:10.1002/anie.200703877

Reference yield:

pyridine-2-carbaldehyde (1121-60-4) + 8-amino quinoline (578-66-5) + tetrakis(acetonitrile)copper(I)tetrafluoroborate + 1,10-phenanthroline-2,9-dicarboxaldehyde (57709-62-3) + p-toluidine (106-49-0,12221-03-3) → [Cu((4-methylphenyl)pyridin-2-ylmethylene-amine)2](1+) (181063-25-2) + (C12H6N2(CHNC9H6N)2)2Cu3(3+) (899795-23-4)

Guidance literature:

In dimethylsulfoxide-d6; [D₃]acetonitrile; in capped NMR tube C7H7(NH2), C9H9N(NH2), C5H4N(CHO), C12H6N2(CHO)2, Cu(CH3CN)4(BF4) (2+4:2+2:4) (CD3CN), (Ar); kept overnight at room temp., at50°C for 50 h; volume reduced under vac.; ppt. dissolution (DMSO -D6), kept at 50°C for 24 h; monitored by (1)HNMR over 7 d;

DOI:10.1002/anie.200703877

upstream raw materials:

pyridine-2-carbaldehyde

8-amino quinoline

1,10-phenanthroline-2,9-dicarboxaldehyde

p-toluidine