[(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH₂SiMe₃)]

Base Information

Chemical Name:[(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH₂SiMe₃)]
CAS No.:844642-16-6
Molecular Formula:C₂₉H₃₈CoN₃Si
Molecular Weight:515.72
Hs Code.:

[(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH<sub>2</sub>SiMe<sub>3</sub>)]

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Chemical Property of [(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH₂SiMe₃)]

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Technology Process of [(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH₂SiMe₃)]

There total 3 articles about [(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH₂SiMe₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 204203-16-7
2,6-bis(1-(2,6-dimethylphenylimino)ethyl)pyridine

: 1221276-10-3
[Co(CH₂SiMe₃)₂(pyridine)₂]

: 844642-16-6
[Co(CH₂Si(CH₃)3)(C₅H₃N(C(CH₃)N(C₆H₃(CH₃)2))2)]

Guidance literature:: In diethyl ether; (N2 or Ar); a soln. of Co complex cooled to -30°C, a soln. of ligand added slowly at -30°C, allowed to warm to room temp., stirredfor 1 h; filtered, evapd. (vac.), dissolved in Et2O/pentane, concd., hexane added, cooled to -35°C overnight, decanted, recrystd. (toluene/hexane); elem. anal.;
DOI:10.1021/om901045s

Reference yield:

: 436857-75-9
dichloro(2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine)cobalt(II)

: 1822-00-0
trimethylsilylmethyllithium

: 844642-16-6
[Co(CH₂Si(CH₃)3)(C₅H₃N(C(CH₃)N(C₆H₃(CH₃)2))2)]

Guidance literature:: In hexane; under Ar, Schlenk setup, metal salt added in soln. of LiCH2SiMe3 in hexane (1:2), stirred for 1 h; filtered, evapd., NMR;
DOI:10.1002/ejic.200300569

Reference yield:

: (tetramethylethylenediamine)Co(CH₂Si(CH₃)3)2

: 844642-16-6
[(2,6-bis(2,6-dimethylphenyliminoethyl)pyridine)Co(CH₂SiMe₃)]

Guidance literature:: In not given; (Ar); using Schlenk techniques; according to: Zhu, D.; Janssen, F.F.B.J.; Budzelaar, P.H.M. Organometallics 2010, 29, 1897-1908;
DOI:10.1021/om300182c