methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate

Base Information

• Chemical Name: methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate
• CAS No.: 106633-10-7
• Molecular Formula: C₁₄H₁₅NO₇Zn
• Molecular Weight: 374.666
• Mol file: 106633-10-7.mol

Synonyms:

Chemical Property of methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate

There total 1 articles about methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

DL-glutamic acid-5-methyl ester (1499-55-4,6461-04-7,14487-45-7) + zinc diacetate (557-34-6) + water (7732-18-5) + Benzoylformic acid (611-73-4) → methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate (106633-10-7)

Guidance literature:

In ethanol; water; addn. of phenylglyoxylic acid to suspension of monomethyl glutamate in aq. ethanol, stirring for 30 min at 25°C, addn. of Zn acetate in aq. ethanol, stirring at room temp. for 2-4 h, pptn., filtration;; drying in vac. over P2O5; crystn. from H2O/ethanol; elem. anal.;;

DOI:10.1039/P19860001669

Reference yield:

methyl N-(α-carboxybenzylidene)glutamatozinc(II) monohydrate (106633-10-7) → ZnC14H15NO7 (106529-15-1)

Guidance literature:

With triethylamine; In pyridine; isomerisation in soln.; storage soln. of Zn complex in dry pyridine containing triethylamine at room temp. for 8 h, removal of pyridine at roomtemp.;; crystn. from H2O;;

DOI:10.1039/P19860001669

upstream raw materials:

DL-glutamic acid-5-methyl ester

zinc diacetate

water

Benzoylformic acid

Downstream raw materials:

ZnC₁₄H₁₅NO₇