C₆₈H₅₈N₆

Base Information

• Chemical Name: C₆₈H₅₈N₆
• CAS No.: 1329612-03-4
• Molecular Formula: C₆₈H₅₈N₆
• Molecular Weight: 959.249
• Mol file: 1329612-03-4.mol

Synonyms:

Chemical Property of C₆₈H₅₈N₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₈H₅₈N₆

There total 5 articles about C₆₈H₅₈N₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,7-di-tert-butyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene (76626-75-0) → C68H58N6 (1329612-03-4)

Guidance literature:

Multi-step reaction with 5 steps

1.1: N-Bromosuccinimide

2.1: n-butyllithium / diethyl ether; hexane / 1 h / -78 °C / Inert atmosphere

2.2: 48 h / 20 °C / Inert atmosphere

3.1: hydrogenchloride; water / diethyl ether; hexane / 3 h

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; toluene / 36 h / Inert atmosphere; Reflux

5.1: acetonitrile / 0 °C / Irradiation

With hydrogenchloride; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; water; sodium carbonate; In diethyl ether; hexane; water; toluene; acetonitrile; 4.1: Suzuki coupling;

DOI:10.1021/ic2003904

Reference yield:

4,9-dibromo-2,7-di-tert-butyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene (181486-12-4) → C68H58N6 (1329612-03-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: n-butyllithium / diethyl ether; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 48 h / 20 °C / Inert atmosphere

2.1: hydrogenchloride; water / diethyl ether; hexane / 3 h

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; toluene / 36 h / Inert atmosphere; Reflux

4.1: acetonitrile / 0 °C / Irradiation

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; water; sodium carbonate; In diethyl ether; hexane; water; toluene; acetonitrile; 3.1: Suzuki coupling;

DOI:10.1021/ic2003904

Reference yield:

2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene (1329611-71-3) → C68H58N6 (1329612-03-4)

Guidance literature:

In acetonitrile; at 0 ℃; Irradiation;

DOI:10.1021/ic2003904

upstream raw materials:

2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

4,9-[B(OH)2]2DHP

4,9-[B(OnBu)2]2DHP

2,7-di-tert-butyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

Downstream raw materials:

2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene