[(2S,3S)-2,3-dimethylcyclopropyl]benzene

Base Information

Chemical Name:[(2S,3S)-2,3-dimethylcyclopropyl]benzene
CAS No.:7653-95-4
Molecular Formula:C₁₁H₁₄
Molecular Weight:146.232
Hs Code.:
DSSTox Substance ID:DTXSID901239483
Nikkaji Number:J818.391K

Synonyms:7653-95-4;DTXSID901239483;Benzene, (2,3-dimethylcyclopropyl)-, (1alpha,2alpha,3beta)-

Suppliers and Price of [(2S,3S)-2,3-dimethylcyclopropyl]benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(2S,3S)-2,3-dimethylcyclopropyl]benzene

Chemical Property:

XLogP3:3.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:146.109550447
Heavy Atom Count:11
Complexity:125

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1C(C1C2=CC=CC=C2)C
Isomeric SMILES:C[C@H]1[C@@H](C1C2=CC=CC=C2)C

Technology Process of [(2S,3S)-2,3-dimethylcyclopropyl]benzene

There total 10 articles about [(2S,3S)-2,3-dimethylcyclopropyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 624-64-6
trans-2-Butene

: 100-44-7
benzyl chloride

: 7653-95-4,7653-96-5,25181-26-4,30836-82-9
1,2-cis,trans-Dimetrhyl-3-phenylcyclopropan

Guidance literature:: With tetramethylpiperidine; methyllithium; In diethyl ether; for 3h; Ambient temperature;
DOI:10.1021/ja9631110

Reference yield:

: 100-52-7
benzaldehyde

: 7653-95-4,7653-96-5,25181-26-4,30836-82-9
1,2-cis,trans-Dimetrhyl-3-phenylcyclopropan

Guidance literature:: Multi-step reaction with 3 steps

1: methanol / 0.5 h

2: 1.) sodium methoxide / 1.) methanol, 2.) vacuum pyrolysis

3: benzophenone / 0.25 h / Irradiation

With sodium methylate; benzophenone; In methanol;
DOI:10.1021/ja00525a025

Reference yield:

: 1666-17-7
benzaldehyde p-toluenesulfonylhydrazone

: 7653-95-4,7653-96-5,25181-26-4,30836-82-9
1,2-cis,trans-Dimetrhyl-3-phenylcyclopropan

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) sodium methoxide / 1.) methanol, 2.) vacuum pyrolysis

2: benzophenone / 0.25 h / Irradiation

With sodium methylate; benzophenone;
DOI:10.1021/ja00525a025