cis-chlorobis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate

Base Information

Chemical Name:cis-chlorobis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate
CAS No.:128389-45-7
Molecular Formula:C₃₄H₃₈ClO₂P₂Pd*ClO₄
Molecular Weight:781.946
Hs Code.:

Synonyms:

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Chemical Property of cis-chlorobis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate

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Technology Process of cis-chlorobis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate

There total 5 articles about cis-chlorobis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: cis-bis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-O,P}palladium(II)-bis(perchlorate)

: 128389-41-3
{PdCl₂((C₆H₅)2PCH₂C₄H₇O)2}

: 128389-45-7
cis-chlorobis{diphenyl(tetrahydrofuran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate

Guidance literature:: In dichloromethane; equimolar amts. (0.33 mmol) of the educts were dissolved in dry CH2Cl2 and stirred for 5 min (exclusion of air);; the solvent was removed in vac., the residue stirred with diethyl ether/n-pentane (1:1) for about 12 h; the the solvent was decanted and the residue dried in vac.; elem. anal.;;;

Reference yield: 93.0%

: 14242-05-8
silver perchlorate monohydrate

: 128389-41-3
trans-dichlorobis{diphenyl(2-tetrahydrofuranylmethyl)phosphane}palladium(II)

: 128389-45-7
trans-chlorobis{diphenyl(2-tetrahydrofuranylmethyl)phosphane-P;O',P'}palladium(II) perchlorate

Guidance literature:: In dichloromethane; byproducts: AgCl; dropwise addn. of AgClO4*H2O soln. to Pd complex soln. under Ar, 0.25h; stirring, 0.5h; filtration; evapn.; stirring with ether, 30h; filtration; drying (high vac.); recrystn. (ether-THF); elem. anal.;

Reference yield:

: 91533-65-2
diphenyl(tetrahydro-2-furanylmethyl)phosphane

: 128389-45-7
trans-chlorobis{diphenyl(2-tetrahydrofuranylmethyl)phosphane-P;O',P'}palladium(II) perchlorate

Guidance literature:: Multi-step reaction with 3 steps

1: dichloromethane

2: dichloromethane

3: tetrahydrofuran

In tetrahydrofuran; dichloromethane;