Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)CF₃SO₃

Base Information

• Chemical Name: Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)CF₃SO₃
• CAS No.: 1064078-53-0
• Molecular Formula: CF₃O₃S*C₇₉H₈₃CuN₃O
• Molecular Weight: 1303.16
• Mol file: 1064078-53-0.mol

Synonyms:

Chemical Property of Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)CF₃SO₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)CF₃SO₃

There total 1 articles about Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3((CH₂)4O)CF₃SO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.4%

copper(I) trifluoromethanesulfonate benzene (37234-97-2) + 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide (1064078-46-1) → Cu(((CH3)3C6H2)2C6H3NC)3((CH2)4O)(1+)*CF3SO3(1-)=Cu(((CH3)3C6H2)2C6H3NC)3((CH2)4O)CF3SO3 (1064078-53-0)

Guidance literature:

In tetrahydrofuran; under N2 atm. to soln. Cu complex in THF was added soln. ligand in THF, mixt. was stirred for 1 h; mixt. was evapd. under vac., residue was dissolved in THF, filtered, kept at -35°C for 12 h, ppt. was collected, dried in vac.; elem. anal.;

DOI:10.1021/ic8010986

Reference yield:

Cu(((CH3)3C6H2)2C6H3NC)3((CH2)4O)(1+)*CF3SO3(1-)=Cu(((CH3)3C6H2)2C6H3NC)3((CH2)4O)CF3SO3 (1064078-53-0) + tetrabutyl-ammonium chloride (1112-67-0) → Cu(((CH3)3C6H2)2C6H3NC)2Cl (1064078-50-7)

Guidance literature:

In tetrahydrofuran; under N2 atm. to soln. Bu4NCl in THF was added soln. Cu complex in THF, mixt. was stirred overnight; mixt. was evapd. under vac., residue was subjected 2 cycle slurrying in n-pentane, evapd, mixt. was stirred for 2 h in C6D6, filtered, monitoring by NMR spectroscopy;

DOI:10.1021/ic8010986

Reference yield:

Cu(((CH3)3C6H2)2C6H3NC)3((CH2)4O)(1+)*CF3SO3(1-)=Cu(((CH3)3C6H2)2C6H3NC)3((CH2)4O)CF3SO3 (1064078-53-0) + lithium chloride → Cu(((CH3)3C6H2)2C6H3NC)2Cl (1064078-50-7)

Guidance literature:

In tetrahydrofuran; under N2 atm. to slurry LiCl in THF was added soln. Cu complex in THF, mixt. was stirred overnight; mixt. was evapd. under vac., residue was subjected 2 cycle slurrying in Et2O, evapd, mixt. was stirred for 2 h in C6D6, filtered, monitoring by NMR spectroscopy;

DOI:10.1021/ic8010986

upstream raw materials:

copper(I) trifluoromethanesulfonate benzene

2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide

Downstream raw materials:

Cu(((CH₃)3C₆H₂)2C₆H₃NC)2Cl

Cu(((CH₃)3C₆H₂)2C₆H₃NC)3(C₆H₆)⁽¹⁺⁾*CF₃SO₃^(1-)=Cu(((CH₃)3C₆H₂)2C₆H₃NC)3(C₆H₆)CF₃SO₃