(E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

Base Information

Chemical Name:(E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane
CAS No.:144264-98-2
Molecular Formula:C₁₆H₁₇ClO₃S
Molecular Weight:324.828
Hs Code.:

(E)-endo-2-<methxoy(thiocarbonyl)oxy>-3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

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Chemical Property of (E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

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Technology Process of (E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

There total 10 articles about (E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: 1067-52-3
tributyltin methoxide

: 144265-06-5,144302-06-7
(E)-3'-(4-chlorophenyl)-endo-2--bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

: 144264-98-2
(E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

Guidance literature:: With 2,2'-azobis(isobutyronitrile); In toluene; for 1.5h; Heating;
DOI:10.1016/S0040-4020(01)89879-3

Reference yield:

: 497-38-1
Norbornan-2-on

: 144264-98-2
(E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / KOH / ethanol / 1 h / Heating

2: 53 percent / CeCl₃, NaBH₄ / methanol

3: 30 percent / mCPBA, NaHCO₃ / CH₂Cl₂ / 4 h / Ambient temperature

4: 69 percent / benzene / 3 h / Heating

5: 26 percent / AIBN / toluene / 1.5 h / Heating

With potassium hydroxide; sodium tetrahydroborate; cerium(III) chloride; 2,2'-azobis(isobutyronitrile); sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; ethanol; dichloromethane; toluene; benzene;
DOI:10.1016/S0040-4020(01)89879-3

Reference yield:

: 104-88-1
4-chlorobenzaldehyde

: 144264-98-2
(E)-endo-2--3'-(4-chlorophenyl)bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / KOH / ethanol / 1 h / Heating

2: 53 percent / CeCl₃, NaBH₄ / methanol

3: 30 percent / mCPBA, NaHCO₃ / CH₂Cl₂ / 4 h / Ambient temperature

4: 69 percent / benzene / 3 h / Heating

5: 26 percent / AIBN / toluene / 1.5 h / Heating

With potassium hydroxide; sodium tetrahydroborate; cerium(III) chloride; 2,2'-azobis(isobutyronitrile); sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; ethanol; dichloromethane; toluene; benzene;
DOI:10.1016/S0040-4020(01)89879-3