(η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane)

Base Information

• Chemical Name: (η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane)
• CAS No.: 265122-96-1
• Molecular Formula: C₄₁H₅₂MoP₂
• Molecular Weight: 702.751
• Mol file: 265122-96-1.mol

Synonyms:

Chemical Property of (η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane)

There total 1 articles about (η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

lithium aluminium tetrahydride (16853-85-3) + (η5-pentaethylcyclopentadienyl)MoCl4 (287411-87-4) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → (η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane) (265122-96-1)

Guidance literature:

With methanol; In diethyl ether; toluene; byproducts: H2; (Ar); dppe added to soln. of C5(C2H5)5MoCl4; LiAlH4 added; stirred overnight; MeOH added dropwise; stirred for 1 h at room temp.; evapd. to dryness; extd. (pentane); filterd; ppt.; filtered off; washed(cold pentane); dried under reduced pressure; elem. anal.;

DOI:10.1016/S0020-1693(99)00584-8

Reference yield: 64.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + (η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane) (265122-96-1) → [(η5-pentaethylcyclopentadienyl)MoH4(1,2-(diphenylphosphino)ethane)][BF4] (287411-89-6)

Guidance literature:

In diethyl ether; (Ar); HBF4*OEt2 added at room temp.; ppt. immediately; filtered; washed (pentane); dried in vacuo;

DOI:10.1016/S0020-1693(99)00584-8

Reference yield: 55.0%

(η5-pentaethylcyclopentadienyl)molybdenum(IV)H3(1,2-(diphenylphosphino)ethane) (265122-96-1) + water (7732-18-5) → (η5-pentaethylcyclopentadienyl)bis(hydroxido)(1,2-bis(diphenylphosphino)ethane)molybdenum (265122-93-8)

Guidance literature:

With (C₅H₅)2FeBF₄; triethylamine; In tetrahydrofuran; byproducts: (C5H5)2Fe; under inert atm.; soln. of Mo-complex in THF at -78°C was transferred to soln. of Cp2FeBF4, stirred at room temp. for 15 min, evapd. in vacuo, residue washed with pentane, dissolved in wet THF, NEt3 added, stirred for 90 min; evapd. to dryness, residue extracted with pentane, filtered through Celite, filtrate concd. in vacuo, crystn. on cooling at -12°C overnight, dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(99)00539-2

upstream raw materials:

lithium aluminium tetrahydride

(η5-pentaethylcyclopentadienyl)MoCl4

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

[(η5-pentaethylcyclopentadienyl)molybdenum(IV)H2(1,2-(diphenylphosphino)ethane)(acetonitrile)][BF4]

[(η5-pentaethylcyclopentadienyl)MoH4(1,2-(diphenylphosphino)ethane)][BF4]

(η5-pentaethylcyclopentadienyl)bis(hydroxido)(1,2-bis(diphenylphosphino)ethane)molybdenum