Me₃Sn-Mn(CO)4(triphenyl phosphite)

Base Information

• Chemical Name: Me₃Sn-Mn(CO)4(triphenyl phosphite)
• CAS No.: 85362-14-7
• Molecular Formula: C₂₅H₂₄MnO₇PSn
• Molecular Weight: 641.083
• Mol file: 85362-14-7.mol

Synonyms:

Chemical Property of Me₃Sn-Mn(CO)4(triphenyl phosphite)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Me₃Sn-Mn(CO)4(triphenyl phosphite)

There total 2 articles about Me₃Sn-Mn(CO)4(triphenyl phosphite) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Mn2(CO)8(triphenyl phosphite)2 (15529-62-1,15228-70-3) + trimethyltin(IV)chloride (1066-45-1) → Me3Sn-Mn(CO)4(triphenyl phosphite) (85362-14-7,110902-15-3)

Guidance literature:

With sodium amalgame; In tetrahydrofuran; under N2, (Mn(CO)4P(OPh)3)2 dissolved in THF, reduced by stirring over 1% Na amalgam, supernatant decanted, Me3SnCl in THF added with stirring,stirred overnight; filtered, vac.-evapd., extd. with hexane, concd. in vac.;

DOI:10.1246/bcsj.56.87

Reference yield:

(CH3)3SnMn(CO)3(P(OC6H5)3)2 (68033-47-6) → fac-cis-(PhO)2P(OC6H4)Mn(CO)3(triphenyl phosphite) + Me3Sn-Mn(CO)4(triphenyl phosphite) (85362-14-7,110902-15-3) + (PhO)2P(OC6H4)Mn(CO)2(triphenyl phosphite)2 (76114-14-2,88082-02-4)

Guidance literature:

In benzene; Irradiation (UV/VIS); under Ar, educt dissolved in benzene, photolyzed for 8 h with Riko 100 W high-pressure Hg lamp; filtered, evapd. in vac., chromd. (Florisil, hexane-benzene), evapd., dissolved in benzene, cyclohexane added, stored in refrigerator for several weeks; elem. anal.;

DOI:10.1246/bcsj.56.87

upstream raw materials:

(CH₃)3SnMn(CO)3(P(OC₆H₅)3)2

Mn₂(CO)8(triphenyl phosphite)2

trimethyltin(IV)chloride