2,6-dimethyldecyl tosylate

Base Information

• Chemical Name: 2,6-dimethyldecyl tosylate
• CAS No.: 121246-25-1
• Molecular Formula: C₁₉H₃₂O₃S
• Molecular Weight: 340.527
• Mol file: 121246-25-1.mol

Synonyms:

Chemical Property of 2,6-dimethyldecyl tosylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-dimethyldecyl tosylate

There total 6 articles about 2,6-dimethyldecyl tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Citronellol (106-22-9) → 2,6-dimethyldecyl tosylate (121246-25-1)

Guidance literature:

Multi-step reaction with 5 steps

1: 19.4 g / pyridine / 0 - 20 °C

2: 8.03 g / dilithium tetrachlorocuprate / tetrahydrofuran / 14 h / -78 - 20 °C

3: SeO₂; salicylic acid; t-BuOOH / CH₂Cl₂ / 9 h / 20 °C

4: H₂ / PtO₂ / ethanol / 36 h / Heating

5: 7.32 g / pyridine / 0 - 20 °C

With pyridine; tert.-butylhydroperoxide; selenium(IV) oxide; dilithium tetrachlorocuprate; hydrogen; salicylic acid; platinum(IV) oxide; In tetrahydrofuran; ethanol; dichloromethane;

DOI:10.1271/bbb.64.2474

Reference yield:

(+/-)-citronellyl tosylate (41144-01-8) → 2,6-dimethyldecyl tosylate (121246-25-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 8.03 g / dilithium tetrachlorocuprate / tetrahydrofuran / 14 h / -78 - 20 °C

2: SeO₂; salicylic acid; t-BuOOH / CH₂Cl₂ / 9 h / 20 °C

3: H₂ / PtO₂ / ethanol / 36 h / Heating

4: 7.32 g / pyridine / 0 - 20 °C

With pyridine; tert.-butylhydroperoxide; selenium(IV) oxide; dilithium tetrachlorocuprate; hydrogen; salicylic acid; platinum(IV) oxide; In tetrahydrofuran; ethanol; dichloromethane;

DOI:10.1271/bbb.64.2474

Reference yield:

2,6-dimethyl-2-decene (214126-59-7) → 2,6-dimethyldecyl tosylate (121246-25-1)

Guidance literature:

Multi-step reaction with 3 steps

1: SeO₂; salicylic acid; t-BuOOH / CH₂Cl₂ / 9 h / 20 °C

2: H₂ / PtO₂ / ethanol / 36 h / Heating

3: 7.32 g / pyridine / 0 - 20 °C

With pyridine; tert.-butylhydroperoxide; selenium(IV) oxide; hydrogen; salicylic acid; platinum(IV) oxide; In ethanol; dichloromethane;

DOI:10.1271/bbb.64.2474

upstream raw materials:

p-toluenesulfonyl chloride

2,6-dimethyl-1-decanol

Citronellol

(+/-)-citronellyl tosylate

Refernces