Technology Process of C35H50O7Si3
There total 12 articles about C35H50O7Si3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 4 steps
1: pyridine; DMAP
2: NMO; OsO4; H2O / tetrahydrofuran / 20 °C
3: Zn; NH4Cl; H2O / tetrahydrofuran / Heating
4: dimethylformamide / 80 °C
With
pyridine; dmap; osmium(VIII) oxide; N-methyl-2-indolinone; water; ammonium chloride; zinc;
In
tetrahydrofuran; N,N-dimethyl-formamide;
1: Acylation / 2: Oxidation / 3: Ring cleavage / 4: Substitution;
DOI:10.1039/a905631i
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194796-30-0
(+)-(1R,4S,4aR,5S,8aS)-5-tert-Butyldimethylsilyloxy-1,4,4a,6,7,8-hexahydro-endo-1,4-methanonaphthalen-8(5H)-one
- Guidance literature:
-
Multi-step reaction with 11 steps
1: 89 percent / NaH / tetrahydrofuran / 20 °C
2: 82 percent / O2; KF; (EtO)3P / dimethylsulfoxide
3: NaBH4 / methanol; tetrahydrofuran / -15 °C
4: NBS / CH2Cl2 / -15 °C
5: 84 percent / POCl3; pyridine / 50 °C
6: DIBAL-H / toluene / -78 °C
7: Bu4NF / tetrahydrofuran / 20 °C
8: pyridine; DMAP
9: NMO; OsO4; H2O / tetrahydrofuran / 20 °C
10: Zn; NH4Cl; H2O / tetrahydrofuran / Heating
11: dimethylformamide / 80 °C
With
pyridine; dmap; potassium fluoride; sodium tetrahydroborate; N-Bromosuccinimide; osmium(VIII) oxide; N-methyl-2-indolinone; tetrabutyl ammonium fluoride; water; oxygen; sodium hydride; diisobutylaluminium hydride; ammonium chloride; zinc; triethyl phosphite; trichlorophosphate;
In
tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene;
1: Condensation / 2: Oxidation / 3: Reduction / 4: Bromination / 5: Dehydration / 6: Reduction / 7: desilylation / 8: Acylation / 9: Oxidation / 10: Ring cleavage / 11: Substitution;
DOI:10.1039/a905631i
- Guidance literature:
-
Multi-step reaction with 4 steps
1: pyridine; DMAP
2: NMO; OsO4; H2O / tetrahydrofuran / 20 °C
3: Zn; NH4Cl; H2O / tetrahydrofuran / Heating
4: dimethylformamide / 80 °C
With
pyridine; dmap; osmium(VIII) oxide; N-methyl-2-indolinone; water; ammonium chloride; zinc;
In
tetrahydrofuran; N,N-dimethyl-formamide;
1: Acylation / 2: Oxidation / 3: Ring cleavage / 4: Substitution;
DOI:10.1039/a905631i
