[(PNP(Ph))Ni(S₂CNEt₂)](BF₄)

Base Information

• Chemical Name: [(PNP(Ph))Ni(S₂CNEt₂)](BF₄)
• CAS No.: 930093-13-3
• Molecular Formula: BF₄*C₃₂H₃₇N₂NiP₂S₂
• Molecular Weight: 721.233
• Mol file: 930093-13-3.mol

Synonyms:

Chemical Property of [(PNP(Ph))Ni(S₂CNEt₂)](BF₄)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(PNP(Ph))Ni(S₂CNEt₂)](BF₄)

There total 1 articles about [(PNP(Ph))Ni(S₂CNEt₂)](BF₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ni(BF4)2*6.5 acetonitrile + sodium N,N-diethyldithiocarbamate (148-18-5) + [N,N-bis(diphenylphospinomethyl)aminomethane] (76645-79-9) → [(PNP(Ph))Ni(S2CNEt2)](BF4) (930093-13-3)

Guidance literature:

In acetonitrile; (N2); Ni complex added to a soln. of ligands, stirred at room temp.; filtered, evapd. (vac.), dissolved in MeCN, pptd. (Et2O), filtered, washed (Et2O);

DOI:10.1021/ic061740x

Reference yield:

[(PNP(Ph))Ni(S2CNEt2)](BF4) (930093-13-3) → Ni(PNP(Ph))2 (930093-19-9)

Guidance literature:

With H₂; In acetonitrile; under 0.82 atm of H2 in the presence of tetramethylguanidine for ca 1 wk; obtained as a mixt.;

DOI:10.1021/ic061740x

upstream raw materials:

sodium N,N-diethyldithiocarbamate

[N,N-bis(diphenylphospinomethyl)aminomethane]

Downstream raw materials:

Ni(PNP(Ph))2