FeBr₂(N(Si(CH₃)2CH₂P(C₆H₅)2)2)

Base Information

• Chemical Name: FeBr₂(N(Si(CH₃)2CH₂P(C₆H₅)2)2)
• CAS No.: 206666-49-1
• Molecular Formula: C₃₀H₃₆Br₂FeNP₂Si₂
• Molecular Weight: 744.396
• Mol file: 206666-49-1.mol

Synonyms:

Chemical Property of FeBr₂(N(Si(CH₃)2CH₂P(C₆H₅)2)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of FeBr₂(N(Si(CH₃)2CH₂P(C₆H₅)2)2)

There total 3 articles about FeBr₂(N(Si(CH₃)2CH₂P(C₆H₅)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

iron (III) bromide (10031-26-2) + ((C6H5)2PCH2Si(CH3)2)2N(1-)*Li(1+)=((C6H5)2PCH2Si(CH3)2)2NLi (77617-69-7) → FeBr2(N(Si(CH3)2CH2P(C6H5)2)2) (206666-49-1)

Guidance literature:

In diethyl ether; N2 or Ar-atmosphere; stirring (room temp., overnight); evapn. (vac.), extg. (toluene), filtering, pptn. on hexanes addn., crystn. (overnight); elem. anal.;

DOI:10.1021/om970665i

Reference yield: 40.0%

FeBr(N(Si(CH3)2CH2P(C6H5)2)2) (206666-44-6) + benzyl bromide (100-39-0) → FeBr2(N(Si(CH3)2CH2P(C6H5)2)2) (206666-49-1)

Guidance literature:

In toluene; N2 or Ar-atmosphere; stirring (overnight); decanting, filtering, crystn. on hexanes addn. (overnight); elem. anal.;

DOI:10.1021/om970665i

Reference yield: 37.0%

FeCl(N(Si(CH3)2CH2P(C6H5)2)2) (206666-43-5) + benzyl bromide (100-39-0) → FeBr2(N(Si(CH3)2CH2P(C6H5)2)2) (206666-49-1)

Guidance literature:

In toluene; N2 or Ar-atmosphere; stirring (overnight); decanting, filtering, crystn. on hexanes addn. (overnight); elem. anal.;

DOI:10.1021/om970665i

upstream raw materials:

iron (III) bromide

((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi

FeBr(N(Si(CH₃)2CH₂P(C₆H₅)2)2)

benzyl bromide