[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]⁽¹⁺⁾*B(C₆F₅)4^(1-)=[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]B(C₆F₅)4

Base Information

• Chemical Name: [(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]⁽¹⁺⁾*B(C₆F₅)4^(1-)=[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]B(C₆F₅)4
• CAS No.: 881013-66-7
• Molecular Formula: C₂₂H₄₂N₃Zr*C₂₄BF₂₀
• Molecular Weight: 1118.86
• Mol file: 881013-66-7.mol

Synonyms:

Chemical Property of [(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]⁽¹⁺⁾*B(C₆F₅)4^(1-)=[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]B(C₆F₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]⁽¹⁺⁾*B(C₆F₅)4^(1-)=[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]B(C₆F₅)4

There total 2 articles about [(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]⁽¹⁺⁾*B(C₆F₅)4^(1-)=[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)]B(C₆F₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NC(CH3)3)] (881013-69-0) + N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate → [(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)](1+)*B(C6F5)4(1-)=[(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)]B(C6F5)4 (881013-66-7)

Guidance literature:

In chlorobenzene; B compd. (1 equiv.) was added to soln. of Zr complex in chlorobenzene;

DOI:10.1021/om051007y

Reference yield: 91.0%

[(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)2] (881013-67-8) + trityl tetrakis(pentafluorophenyl)borate → [(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)](1+)*B(C6F5)4(1-)=[(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)]B(C6F5)4 (881013-66-7)

Guidance literature:

In chlorobenzene;

DOI:10.1021/om051007y

Reference yield: 100.0%

[(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)](1+)*B(C6F5)4(1-)=[(C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC(CH3)3)]B(C6F5)4 (881013-66-7) + tert-butylamine (75-64-9) → (C5(CH3)5)Zr(CH3C(NCH(CH3)2)2)(NHC4H9)(NH2C4H9)(1+)*B(C6F5)4(1-)=[(C5(CH3)5)Zr(CH3C(NC3H7)2)(NHC4H9)(NH2C4H9)]B(C6F5)4 (881013-71-4)

Guidance literature:

In toluene; amine (1 equiv.) and Zr complex were reacted in toluene;

DOI:10.1021/om051007y

upstream raw materials:

[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NC(CH₃)3)]

[(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC(CH₃)3)2]

Downstream raw materials:

(C₅(CH₃)5)Zr(CH₃C(NCH(CH₃)2)2)(NHC₄H₉)(NH₂C₄H₉)⁽¹⁺⁾*B(C₆F₅)4^(1-)=[(C₅(CH₃)5)Zr(CH₃C(NC₃H₇)2)(NHC₄H₉)(NH₂C₄H₉)]B(C₆F₅)4