10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin

Base Information

• Chemical Name: 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin
• CAS No.: 86318-00-5
• Molecular Formula: C₁₉H₁₃N₃O₂
• Molecular Weight: 315.331
• Mol file: 86318-00-5.mol

Synonyms:

Chemical Property of 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin

There total 8 articles about 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

N-Hydroxy-N'-(4-nitrophenyl)-N-phenylbenzamidin (86317-86-4) + p-toluenesulfonyl chloride (98-59-9) → 1-(4-nitrophenyl)-2-phenyl-1H-1,3-benzimidazole (86317-99-9) + 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin (86318-00-5) + N-<2-(4-Methylphenylsulfonyloxy)phenyl>-N'-(4-nitrophenyl)benzamidin (86317-96-6) + N-<4-(4-Methylphenylsulfonyloxy)phenyl>-N'-(4-nitrophenyl)benzamidin (86317-97-7)

Guidance literature:

With triethylamine; In chloroform; Product distribution; Mechanism; 1) 30 min, 0 deg C, 2) 30 min, 20 deg C; 18O labelling study;

Reference yield: 13.0%

N-Hydroxy-N-(4-nitrophenyl)-N'-phenylbenzamidin (86317-87-5) → 1-(4-nitrophenyl)-2-phenyl-1H-1,3-benzimidazole (86317-99-9) + 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin (86318-00-5) + N-<2-(4-Methylphenylsulfonyloxy)phenyl>-N'-(4-nitrophenyl)benzamidin (86317-96-6) + N-<4-(4-Methylphenylsulfonyloxy)phenyl>-N'-(4-nitrophenyl)benzamidin (86317-97-7)

Guidance literature:

With triethylamine; p-toluenesulfonyl chloride; In chloroform; 1) 30 min, 0 deg C, 2) 30 min, 20 deg C;

Reference yield: 13.0%

N-Hydroxy-N-(4-nitrophenyl)-N'-phenylbenzamidin (86317-87-5) + p-toluenesulfonyl chloride (98-59-9) → 1-(4-nitrophenyl)-2-phenyl-1H-1,3-benzimidazole (86317-99-9) + 10-Nitro-6-phenyl-5H-dibenzo<1,3>diazepin (86318-00-5) + N-<2-(4-Methylphenylsulfonyloxy)phenyl>-N'-(4-nitrophenyl)benzamidin (86317-96-6) + N-<4-(4-Methylphenylsulfonyloxy)phenyl>-N'-(4-nitrophenyl)benzamidin (86317-97-7)

Guidance literature:

With triethylamine; In chloroform; Product distribution; Mechanism; 1) 30 min, 0 deg C, 2) 30 min, 20 deg C; 18O labelling study;

upstream raw materials:

N-Hydroxy-N-(4-nitrophenyl)-N'-phenylbenzamidin

N-Hydroxy-N'-(4-nitrophenyl)-N-phenylbenzamidin

p-toluenesulfonyl chloride

4-Nitro-N-phenylhydroxylamine