E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl

Base Information

• Chemical Name: E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl
• CAS No.: 124019-68-7
• Molecular Formula: C₂₀H₁₈FeO₄
• Molecular Weight: 378.208
• Mol file: 124019-68-7.mol

Synonyms:

Chemical Property of E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl

There total 1 articles about E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

{1-4-η-7-exo-benzoylcycloheptatriene}iron tricarbonyl + potassium hydride + 1-iodo-propane (107-08-4) → {1-4-η-7-exo-n-propyl-7-endo-benzoylheptatriene}iron tricarbonyl + E-{1-4-η-8-phenyl-8-n-propoxyheptafulvene}iron tricarbonyl (124019-68-7,107407-18-1,124019-67-6)

Guidance literature:

In tetrahydrofuran; cycloheptatriene complex dissolved in a slurry of KH (N2), mixt. stirred (1h), filtered (Celite), soln. of 1-iodopropane added (25°C), refluxing (8h); the alkylation at oxygen gave a phenyl-n-propoxy-heptafulvene; filtered (Celite), solvent removed (rot. evapn.), residue chromd. (silica gel, 20:1 petroleum ether/Et2O); elem. anal.; in soln. mixt. E/Z 2.5:1;

DOI:10.1021/ja00157a033

upstream raw materials:

1-iodo-propane