C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3

Base Information

Chemical Name:C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3
CAS No.:92074-22-1
Molecular Formula:C₂₃H₄₀OSn
Molecular Weight:451.28
Hs Code.:

C<sub>6</sub>H<sub>5</sub>CH<sub>2</sub>OCH<sub>2</sub>CH<sub>2</sub>CHCHSn(C<sub>4</sub>H<sub>9</sub>)3

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Chemical Property of C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3

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Technology Process of C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3

There total 7 articles about C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 22273-77-4
((but-3-yn-1-yloxy)methyl)benzene

: tin(ll) chloride

: 92074-22-1,107711-36-4
(E)-4-benzyloxy-1-tributylstannyl-1-butene

Guidance literature:: With methyl magnesium iodide; n-butyllithium; copper(l) cyanide; In tetrahydrofuran; diethyl ether; hexane; soln. of BuLi in hexane added to suspn. of anhyd. SnCl2 in THF at 0 °C, stirred for 20 min, added soln. of MeMgI in Et2O, stirred for 15min, added CuCN, then PhCH2OCH2CH2CCH in THF, stirred for 30 min at 0 °C, poured in satd. aq. NH4Cl; extd. (Et2O), org. layer washed with brine, dried over Na2SO4, concd., chromd. (Al2O3); elem. anal.;
DOI:10.1016/0022-328X(85)87365-4

Reference yield:

: 22273-77-4
((but-3-yn-1-yloxy)methyl)benzene

: 688-73-3
tri-n-butyl-tin hydride

: 107711-36-4,92074-22-1
C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3

: 92074-22-1,107711-36-4
(E)-4-benzyloxy-1-tributylstannyl-1-butene

Guidance literature:: triethyl borane; In hexane; toluene; addn. of Et3B in hexane to a soln. of PhCH2OCH2CH2CCH and n-Bu3SnH in toluene at 25°C under Ar, stirring for 10 h; pouring into water, extg. 3 times with ethyl acetate, washing the combined org. layers with brine, drying over Na2SO4, concg. in vac., preparative TLC on silica gel, 71% combined yield of the isomers, E/Z = 90/10;
DOI:10.1021/ja00242a068

Reference yield:

: 22273-77-4
((but-3-yn-1-yloxy)methyl)benzene

: 688-73-3
tri-n-butyl-tin hydride

: 107711-36-4,92074-22-1
C₆H₅CH₂OCH₂CH₂CHCHSn(C₄H₉)3

: 92074-22-1,107711-36-4
(E)-4-benzyloxy-1-tributylstannyl-1-butene

Guidance literature:: triethyl borane; In hexane; toluene; addn. of Et3B in hexane to a soln. of PhCH2OCH2CH2CCH and n-Bu3SnH in toluene at 25°C under Ar, stirring for 10 h; pouring into water, extg. 3 times with ethyl acetate, washing the combined org. layers with brine, drying over Na2SO4, concg. in vac., preparative TLC on silica gel, 71% combined yield of the isomers, E/Z = 90/10;
DOI:10.1021/ja00242a068