[Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

Base Information

Chemical Name:[Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]]
CAS No.:866338-20-7
Molecular Formula:C₅₅H₄₆N₂O₁₃P₄Ru₃S₂
Molecular Weight:1434.21
Hs Code.:

Synonyms:

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Chemical Property of [Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

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Technology Process of [Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

There total 2 articles about [Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: (PhO)2PN(Me)P(S)(PhO)2

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 866338-18-3
[Ru3(μ3-S)2(μ3-CO)(CO)7[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

: 866338-20-7
[Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

Guidance literature:: With (CH₃)3NO; In toluene; under N2 atm. using Schlenk techniques; mixt. of Ru3(CO)12 and diphosphazane dissolved in toluene; Me3NO (1.1 equiv.) added; soln. heated under reflux for 1.5 h; solvent evapd.; residue dissolved (CH2Cl2); purified by thin-layer chromy. (silica gel, CH2Cl2-petroleum ether (1:1) as eluent); eluted bands sepd.; extd. (CH2Cl2); solvent evapd.; residue crystd. from CH2Cl2 layeredwith petroleum ether; elem. anal.;
DOI:10.1016/j.jorganchem.2005.05.041

Reference yield:

: (PhO)2PN(Me)P(S)(PhO)2

: 866338-18-3
[Ru3(μ3-S)2(μ3-CO)(CO)7[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

: 866338-20-7
[Ru3(μ3-S)2(CO)5[μ-P,P-(PhO)2PN(Me)P(OPh)2]]

Guidance literature:: With (CH₃)3NO; In toluene; under N2 atm. using Schlenk techniques; mixt. of Ru cluster and diphosphazane dissolved in toluene; Me3NO added; soln. heated to boiling; solvent evapd.; residue dissolved (CH2Cl2); purified by thin-layer chromy. (silica gel, CH2Cl2-petroleum ether (1:1) as eluent); eluted bands sepd.; extd. (CH2Cl2); solvent evapd.; residue crystd. from CH2Cl2 layeredwith petroleum ether; elem. anal.;
DOI:10.1016/j.jorganchem.2005.05.041