[nickel(II)(4-thiophenoyphenylglyoxime)2]

Base Information

• Chemical Name: [nickel(II)(4-thiophenoyphenylglyoxime)2]
• CAS No.: 1005756-78-4
• Molecular Formula: C₂₈H₂₂N₄NiO₄S₂
• Molecular Weight: 601.329
• Mol file: 1005756-78-4.mol

Synonyms:

Chemical Property of [nickel(II)(4-thiophenoyphenylglyoxime)2]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [nickel(II)(4-thiophenoyphenylglyoxime)2]

There total 1 articles about [nickel(II)(4-thiophenoyphenylglyoxime)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

nickel(II) chloride hexahydrate + 4-thiophenoxyphenylglyoxime → [nickel(II)(4-thiophenoyphenylglyoxime)2] (1005756-78-4)

Guidance literature:

In ethanol; water; soln. of Ni salt in EtOH/H2O added drop by drop to soln. of C14H12N2O2S in hot EtOH with stirring, pH of react. 3.5-4.0, then 5.5-6.0 (1 % NaOH added); kept in water bath at 60°C for 1 h to complete pptn.; ppt. filtered off, washed (H2O, EtOH, and Et2O), dried; elem. anal.;

DOI:10.1134/S1070328407030050

Reference yield: 75.0%

[nickel(II)(4-thiophenoyphenylglyoxime)2] (1005756-78-4) + trifluoroborane diethyl ether (109-63-7) → [nickel(II)((4-thiophenoyphenylglyoxime)(BF2))2]

Guidance literature:

In acetonitrile; in N2 atm.; suspn. of Ni complex in CH3CN refluxed, boron complex added with stirring, refluxed for 30 min; solvent evapd. to dryness, dissolved in dry CH3CN, kept at -18°C overnight; collected by filtration, washed (cold CH3CN and Et2O), dried in vacuo; elem. anal.;

DOI:10.1134/S1070328407030050