[(pentafluorophenyl)₂Pt(μ-PPh₂)₂Pt(triphenylphosphane)]

Base Information

• Chemical Name: [(pentafluorophenyl)₂Pt(μ-PPh₂)₂Pt(triphenylphosphane)]
• CAS No.: 159602-35-4
• Molecular Formula: C₅₄H₃₅F₁₀P₃Pt₂
• Molecular Weight: 1356.94

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Chemical Property of [(pentafluorophenyl)₂Pt(μ-PPh₂)₂Pt(triphenylphosphane)]

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Technology Process of [(pentafluorophenyl)₂Pt(μ-PPh₂)₂Pt(triphenylphosphane)]

There total 1 articles about [(pentafluorophenyl)₂Pt(μ-PPh₂)₂Pt(triphenylphosphane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

perchlorato(triphenylphosphane)silver(I) (73165-02-3,623171-38-0) + [NBu4]2[Pt4(μ-PPh2)4(C6F5)4(μ-Br)2] → silver(I) bromide + [(pentafluorophenyl)2Pt(μ-PPh2)2Pt(triphenylphosphane)] (1184180-44-6,159602-35-4)

Guidance literature:

In dichloromethane; byproducts: (Bu4N)ClO4; to soln. Pt complex in CH2Cl2 Ag complex was added and stirred at room temp. for 15 min; soln. was filtered and evapd. to dryness, Et2O was added, soln. was filtered and evapd. in vacuo, residue was treated with n-hexane, filtered and dried in air;

DOI:10.1021/ic051248y

Reference yield: 60.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + [(pentafluorophenyl)2Pt(μ-PPh2)2Pt(triphenylphosphane)] (1184180-44-6,159602-35-4) + silver perchlorate → [AuPt2(μ-PPh2)2(C6F5)2(PPh3)2]ClO4

Guidance literature:

In dichloromethane; mixt. of Ag salt and Au complex in CH2Cl2 was stirred at 273 K in dark for 1 h; filtered through Celite; Pt complex was added at 273 K; stirred for 5 min; evapd.; hexane added; hexane added; stirred; filtered; washed (hexane); elem. anal.;

DOI:10.1021/ic900415m

Reference yield: 50.0%

cis-bis(diphenylphosphine)bis(pentafluorophenyl)platinum(II) + [(pentafluorophenyl)2Pt(μ-PPh2)2Pt(triphenylphosphane)] (1184180-44-6,159602-35-4) + tetrabutylammonium perchlorate (1923-70-2) → (Bu4N)2[(C6F5)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(C6F5)2]

Guidance literature:

With BuLi; In tetrahydrofuran; hexane; to THF soln. cis-(Pt(C6F5)2(PPh2H)2) was added at -78°C BuLi in hexane, stirred for 15 min, ((C6F5)2Pt(μ-PPh2)2Pt(PPh3)) was added, stirred after reaching room temp. for 1 h, soln. was evapd., residue was dissolved in iPrOH, NBu4ClO4 was added; ppt. was filtered off, washed with iPrOH, and recrystd. from acetone/CHCl3; elem. anal.;

DOI:10.1021/om010407s

upstream raw materials:

perchlorato(triphenylphosphane)silver(I)

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