Tetrabutylammonium perchlorate

Base Information

• Chemical Name: Tetrabutylammonium perchlorate
• CAS No.: 1923-70-2
• Molecular Formula: C16H36N^.ClO4
• Molecular Weight: 341.919
• Hs Code.: 29239000
• European Community (EC) Number: 217-655-5
• DSSTox Substance ID: DTXSID9062065
• Wikidata: Q55574227
• ChEMBL ID: CHEMBL1078234
• Mol file: 1923-70-2.mol

Synonyms:Bu(4)NBr;tetra-n-butylammonium dodecylsulfate;tetra-n-butylammonium hexafluorophosphate;tetrabutylammonium;tetrabutylammonium azide;tetrabutylammonium bromide;tetrabutylammonium chloride;tetrabutylammonium cyanide;tetrabutylammonium fluoride;tetrabutylammonium hydrogen sulfate;tetrabutylammonium hydroxide;tetrabutylammonium iodide;tetrabutylammonium monophosphate;tetrabutylammonium nitrate;tetrabutylammonium perchlorate;tetrabutylammonium sulfate;tetrabutylammonium sulfate (1:1), sodium salt

Chemical Property of Tetrabutylammonium perchlorate

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 211-215 °C
• Refractive Index: 1.6800 (estimate)
• PSA: 74.27000
• Density: 1.0387 (rough estimate)
• LogP: 5.21790
• Sensitive.: Hygroscopic
• Solubility.: acetonitrile: 0.1 g/mL, clear, colorless
• Water Solubility.: Soluble in acetonitrile and ethanol. Very slightly soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 341.2332863
• Heavy Atom Count: 22
• Complexity: 212

Purity/Quality:

98%, ^*data from raw suppliers

Tetrabutylammonium Perchlorate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O, Xi
• Hazard Codes: O,Xi
• Statements: 5-8-36/37/38
• Safety Statements: 17-26-36-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Perchlorates
• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[O-]Cl(=O)(=O)=O
• Uses: Tetrabutylammonium perchlorate is a polarographic supporting electrolyte. Suitable for use as a polarographic supporting electrolyteTetra-n-butylammonium perchlorate is used as a supporting electrolyte in polarographic measurements. Tetrabutylammonium perchlorate is a tetraalkylammonium salt that can be used in phase-transfer catalysis.

Technology Process of Tetrabutylammonium perchlorate

There total 43 articles about Tetrabutylammonium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium perchlorate (1923-70-2)

Guidance literature:

With trimethyl phosphite; perchloric acid; at 0 - 60 ℃; for 15h; Inert atmosphere; neat (no solvent);

DOI:10.1002/ejoc.201200370

Reference yield: 90.0%

(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2 (74436-10-5) + silver perchlorate → cis-[Pd(pentafluorophenyl)2(THF)2] + tetrabutylammonium perchlorate (1923-70-2)

Guidance literature:

In tetrahydrofuran; byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;

Reference yield: 90.0%

N-n-Bu4{Au(C6Cl5)2} + silver perchlorate → [{Au(C6Cl5)2}Ag]n + tetrabutylammonium perchlorate (1923-70-2)

Guidance literature:

In dichloromethane; AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.;

DOI:10.1016/S0020-1693(00)87648-3

upstream raw materials:

tetrabutylammomium bromide

Triethylammonium perchlorate

tetrabutyl-ammonium chloride

tetra(n-butyl)ammonium hydroxide

Downstream raw materials:

[Fe(TPP)(NO)2]ClO₄

[tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate

osmium-tris-4,7-diphenylphenanthroline perchlorate

(C₄H₉)4N⁽¹⁺⁾*[Au(C₆F₅)2(CN)2]^(1-)=(C₄H₉)4N[Au(C₆F₅)2(CN)2]

Refernces

• 1、 Banerjee, Samya,Prasad, Puja,Khan, Imran,Hussain, Akhtar,Kondaiah, Paturu,Chakravarty, Akhil R.. "Mitochondria targeting photocytotoxic oxidovanadium(IV) complexes of curcumin and (acridinyl)dipyridophenazine in visible light". . p. 1195 - 1204. Retrieved 2014.
• 2、 Mitra, Koushambi,Gautam, Srishti,Kondaiah, Paturu,Chakravarty, Akhil R.. "The cis-Diammineplatinum(II) Complex of Curcumin: A Dual Action DNA Crosslinking and Photochemotherapeutic Agent". . p. 13989 - 13993. Retrieved 2016.