trans-iodo(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II)

Base Information

• Chemical Name: trans-iodo(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II)
• CAS No.: 360048-21-1
• Molecular Formula: C₅₉H₅₃IO₂P₂PtSi
• Molecular Weight: 1206.09

Synonyms:

Chemical Property of trans-iodo(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II)

Chemical Property:

Purity/Quality:

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Technology Process of trans-iodo(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II)

There total 1 articles about trans-iodo(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + tert-butyldiphenylsilyl-3-iodobenzoate (360048-19-7) → trans-iodo(tert-butyldiphenylsilylbenzoate-C(3))bis(triphenylphosphine)platinum(II) (360048-21-1)

Guidance literature:

In toluene; the mixt. in toluene was stirred at 75°C for 14 h, allowed to cool to room temp. (N2); reduced in vac., hexane was added, ppt. was filtered off, washed with n-hexane, dried in vac., recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/om010127c

Reference yield: 89.0%

4,7-phenanthroline (230-07-9) + trans-iodo(tert-butyldiphenylsilylbenzoate-C(3))bis(triphenylphosphine)platinum(II) (360048-21-1) + silver trifluoromethanesulfonate (2923-28-6) → trans-μ-4,7-phenanthrolinebis[(tert-butyldiphenylsilylbenzoate-C3)bis(triphenylphosphine)platinum(II)] bis(triflate)

Guidance literature:

In dichloromethane; byproducts: AgI; to a stirred soln. of complex in CH2Cl2 was added AgO3SCF3, the mixt. was stirred at room temp. for 16 h in the absence of light, AgI was filtered off, reduced in vol., phenanthroline was added, the mixt. was stirredfor 1 h at room temp. (N2); the solvent was removed in vac.; elem. anal.;

DOI:10.1021/om010127c

Reference yield: 88.0%

4,4'-bipyridine (553-26-4) + trans-iodo(tert-butyldiphenylsilylbenzoate-C(3))bis(triphenylphosphine)platinum(II) (360048-21-1) + silver trifluoromethanesulfonate (2923-28-6) → trans-μ-4,4'-bipyridinebis[(tert-butyldiphenylsilyl benzoate-C3)bis(triphenylphosphine)platinum(II)] bis(triflate)

Guidance literature:

In dichloromethane; byproducts: AgI; to a stirred soln. of complex in CH2Cl2 was added AgO3SCF3, the mixt. was stirred at room temp. for 16 h in the absence of light, AgI was filtered off, reduced in vol., bipyridine was added, the mixt. was stirred for1 h at room temp. (N2); the solvent was removed in vac.; elem. anal.;

DOI:10.1021/om010127c

upstream raw materials:

tetrakis(triphenylphosphine)platinum

tert-butyldiphenylsilyl-3-iodobenzoate

Downstream raw materials:

trans-(nicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate

trans-(isonicotinic acid)(tert-butyldiphenylsilyl benzoate-C₃)bis(triphenylphosphine)platinum(II) triflate

trans-4,7-phenanthroline(tert-butyldiphenylsilylbenzoate-C⁽³⁾)bis(triphenylphosphine)platinum(II) triflate

trans-(benzoic acid-C₃)(isonicotinic acid)bis(triphenylphosphine)platinum(II) triflate

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