(pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]

Base Information

Chemical Name:(pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]
CAS No.:412348-46-0
Molecular Formula:C₉₀H₁₁₀N₄NiRu
Molecular Weight:1407.65
Hs Code.:

(pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]

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Chemical Property of (pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]

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Technology Process of (pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]

There total 2 articles about (pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 96503-27-4
pentamethylcyclopentadienylruthenium dichloride

: 412348-41-5
nickel(II) 2,3-(β-methylpropeno)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

: 412348-46-0
(pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]

: (Ni((C₂₀H₆N₄)(C₆H₃(C(CH₃)3)2)4(CHC(CH₃)CH)))2

Guidance literature:: With lithium diisopropylamide; In tetrahydrofuran; deprotonated (lithium diisopropylamide); react. with (C5Me5)RuCl2 (room temp., 2-5 d);
DOI:10.1039/b107732e

Reference yield: 25.0%

: 96503-27-4
pentamethylcyclopentadienylruthenium dichloride

: nickel(II) 2,3-(β-methylpropeno)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin methanol water adduct (1/1/2)

: 412348-46-0
(pentamethylcyclopentadienide)ruthenium(II) [1,2-[nickel(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]-3-methyl-cyclopentadienide]

: [nickel(II) 2,3-(β-methylpropeno)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin]2

Guidance literature:: With lithium diisopropylamide; In tetrahydrofuran; lithium diisopropylamide in THF added to a soln. of Ni complex, stirred at 0°C under Ar for 1 h, Ru complex added, stirred at room temp. under air-free conditions for 2 d; filtered, evapd., chromd. (silica gel, CH2Cl2/cyclohexane), chromd. (Sephadex LH-20, THF), recrystd. (CH2Cl2/MeOH); elem. anal.;
DOI:10.1021/ic062303l