trans-(phenyl)methylbis(triethylphosphine)nickel(II)

Base Information

Chemical Name:trans-(phenyl)methylbis(triethylphosphine)nickel(II)
CAS No.:57811-74-2
Molecular Formula:C₁₉H₃₈NiP₂
Molecular Weight:387.148
Hs Code.:

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Chemical Property of trans-(phenyl)methylbis(triethylphosphine)nickel(II)

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Technology Process of trans-(phenyl)methylbis(triethylphosphine)nickel(II)

There total 1 articles about trans-(phenyl)methylbis(triethylphosphine)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: trans-phenylbromobis(triethylphosphine)nickel(II)

: 917-54-4
methyllithium

: 57811-74-2
trans-(phenyl)methylbis(triethylphosphine)nickel(II)

Guidance literature:: With chloro-trimethyl-silane; In diethyl ether; under Ar to an etheral soln. of Ni-complex MeLi in ether was added, stirred for 30 min at temp. below -30°C, trimethylchlorosilane was added; evapd., concd. at -78°C, dried in vac., dissolved in hexane at room temp., filtered, concd., cooled to -78°C, recrystd. from hexane; elem. anal.;
DOI:10.1016/S0022-328X(00)82457-2

Reference yield:

: 57811-74-2
trans-(phenyl)methylbis(triethylphosphine)nickel(II)

: Ni(C₆H₅)(SH)(P(C₂H₅)3)2

Guidance literature:: With hydrogen sulfide; In not given; byproducts: CH4; according to: D. G. Morell, J. K. Kochi, J. Am. Chem. Soc. 97 (1975) 7262;

Reference yield:

: 57811-74-2
trans-(phenyl)methylbis(triethylphosphine)nickel(II)

: 23936-60-9
1,2-bis(dimethylphosphanyl)ethane

: 86823-42-9
(phenyl)methyl(1,2-bis(dimethylphosphino)ethane)nickel(II)

Guidance literature:: In diethyl ether; soln. of Ni complex in Et2O treated with stoich. amt. of ligand below 0°C; recrystd. from C6H6/hexane;
DOI:10.1021/om50004a042