[N,N'-(1,2-dimethyl-1,2-ethanediylidene)(3,5-bis(benzofuran-2-yl)phenyl)amine][η3-2-propenyl]nickel tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Base Information

• Chemical Name: [N,N'-(1,2-dimethyl-1,2-ethanediylidene)(3,5-bis(benzofuran-2-yl)phenyl)amine][η3-2-propenyl]nickel tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
• CAS No.: 724428-41-5
• Molecular Formula: C₃₂H₁₂BF₂₄*C₅₁H₃₇N₂NiO₄
• Molecular Weight: 1663.78
• Mol file: 724428-41-5.mol

Synonyms:

Chemical Property of [N,N'-(1,2-dimethyl-1,2-ethanediylidene)(3,5-bis(benzofuran-2-yl)phenyl)amine][η3-2-propenyl]nickel tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N,N'-(1,2-dimethyl-1,2-ethanediylidene)(3,5-bis(benzofuran-2-yl)phenyl)amine][η3-2-propenyl]nickel tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

There total 1 articles about [N,N'-(1,2-dimethyl-1,2-ethanediylidene)(3,5-bis(benzofuran-2-yl)phenyl)amine][η3-2-propenyl]nickel tetrakis[3,5-bis(trifluoromethyl)phenyl]borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

bis-allylnickel chloride + 2,3-bis(2,6-bis(benzofuran-2-yl)phenylimino)butane + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [N,N'-(1,2-dimethyl-1,2-ethanediylidene)(3,5-bis(benzofuran-2-yl)phenyl)amine][η3-2-propenyl]nickel tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (724428-41-5)

Guidance literature:

In diethyl ether; byproducts: NaCl; (Ar); stirring a mixt. of ligand, nickel complex and boron compd. in Et2O at room temp. for 12 h; filtration through Celite, evapn., washing with pentane, drying; elem. anal.;

DOI:10.1021/om0497902

upstream raw materials:

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate