trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride}

Base Information

• Chemical Name: trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride}
• CAS No.: 105816-72-6
• Molecular Formula: C₂₈H₂₄Cl₂FeO₂P₂
• Molecular Weight: 581.198
• Mol file: 105816-72-6.mol

Synonyms:

Chemical Property of trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride}

There total 6 articles about trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2-bis-(diphenylphosphino)ethane (1663-45-2) + iron(II) chloride → [(1,2-bis(diphenylphosphino)ethane)Fe(CO)2Cl2] (105816-72-6,51684-08-3,51744-70-8)

Guidance literature:

With CO; In tetrahydrofuran; benzene; 3-16 h reflux, then 2.5 h to 6 days at room temp. under CO; recryst. from ether/ or C5H12 / CH2Cl2;

DOI:10.1039/DT9730002103 DOI:10.1021/ic50008a045

Reference yield:

1,2-bis-(diphenylphosphino)ethane (1663-45-2) → trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride} (105816-72-6,51684-08-3,51744-70-8)

Guidance literature:

In tetrahydrofuran;

DOI:10.1039/DT9730002103 DOI:10.1021/ic50008a045

Reference yield:

(CO)2Fe(C6H5)2PCH2CH2P(C6H5)2Cl2 → trans-{bis(diphenylphosphino)ethane dicarbonyl iron(II) chloride} (105816-72-6,51684-08-3,51744-70-8)

Guidance literature:

In acetone; reflux in acetone for 17 h;

DOI:10.1021/ic50008a045

upstream raw materials:

1,2-bis-(diphenylphosphino)ethane

carbon monoxide

formyl radical

Downstream raw materials:

Fe(1,3-propanedithiolate)(CO)₂(dppe)

Fe(1,3-propanedithiolate)(CO)₂(dppe)

Fe(2,-dimethyl-1,3-propanedithiolate )(CO)₂(dppe)

Fe(2,-dimethyl-1,3-propanedithiolate)(CO)₂(dppe)