[Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3]

Base Information

• Chemical Name: [Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3]
• CAS No.: 960069-53-8
• Molecular Formula: C₂₇H₃₅Mo₂O₄P
• Molecular Weight: 646.426
• Mol file: 960069-53-8.mol

Synonyms:

Chemical Property of [Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3]

There total 1 articles about [Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[(η5-cyclopentadienyl)2Mo2(μ-carbonyl)(μ-methoxycarbyne)(μ-dicyclohexylphosphide)] + carbon monoxide (201230-82-2) → [Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3] (960069-53-8,960162-11-2)

Guidance literature:

In toluene; (N2); exposure toluene soln. of molybdenum compd. to CO at 77 K, warmingto room temp., stirring for 14 h; evapn., addn. of CH2Cl2 and petroleum ether, evapn., elem. anal.;

DOI:10.1021/om700735g

Reference yield: 68.0%

[Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3] (960069-53-8,960162-11-2) → [Mo2(η5-cyclopentadienyl)2(μ-dicyclohexylphosphide)(μ-methoxycarbyne)(carbonyl)2] (960069-54-9)

Guidance literature:

In toluene; byproducts: CO; (N2); stirring toluene soln. of molybdenum compd. at 333 K for 45 min; evapn., addn. of CH2Cl2 and petroleum ether, chromy. (alumina, CH2Cl2/petroleum ether (1:2)) at 253 K, evapn., elem. anal.;

DOI:10.1021/om700735g

Reference yield:

[Mo2(cyclopentadienyl)2(μ-methoxycarbyne)(μ-PCy2)(CO)3] (960069-53-8,960162-11-2) → [(η5-cyclopentadienyl)2Mo2(μ-carbonyl)(μ-methoxycarbyne)(μ-dicyclohexylphosphide)]

Guidance literature:

In toluene; (N2); heating toluene soln. of molybdenum compd. above 333 K;

DOI:10.1021/om700735g

upstream raw materials:

carbon monoxide

Downstream raw materials:

[Mo2(η5-cyclopentadienyl)2(μ-dicyclohexylphosphide)(μ-methoxycarbyne)(carbonyl)2]