bis(2-phenylcyclopenta[l]phenanthryl)zirconium dichloride

Base Information

• Chemical Name: bis(2-phenylcyclopenta[l]phenanthryl)zirconium dichloride
• CAS No.: 295805-63-9
• Molecular Formula: C₄₆H₃₀Cl₂Zr
• Molecular Weight: 744.874
• Mol file: 295805-63-9.mol

Synonyms:

Chemical Property of bis(2-phenylcyclopenta[l]phenanthryl)zirconium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis(2-phenylcyclopenta[l]phenanthryl)zirconium dichloride

There total 1 articles about bis(2-phenylcyclopenta[l]phenanthryl)zirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

zirconium(IV) chloride (10026-11-6) + 2-phenylcyclopenta[l]phenanthrene (121221-39-4) → bis(2-phenylcyclopenta[l]phenanthryl)zirconium dichloride (295805-63-9)

Guidance literature:

With n-C₄H₉Li; In tetrahydrofuran; hexane; toluene; under Ar; in a soln. of the ligand in THF was added a soln. of C4H9Li in hexane at -78°C, stirred overnight, evapd. to dryness, washed with C5H12, treated with ZrCl4 in C6H5CH3, stirred (3h, 90°C), cooled to 25°C, stirred overnight; the mixt. was filtered, the residue was washed with C5H12 and THF;

DOI:10.1021/om000149j

upstream raw materials:

zirconium(IV) chloride

2-phenylcyclopenta[l]phenanthrene