1-Bromo-3-(bromomethyl)-5-nitrobenzene

Base Information

Chemical Name:1-Bromo-3-(bromomethyl)-5-nitrobenzene
CAS No.:139194-80-2
Molecular Formula:C7H5Br2NO2
Molecular Weight:294.93
Hs Code.:2904909090
European Community (EC) Number:968-167-0
DSSTox Substance ID:DTXSID90564823
Wikidata:Q82449657
Mol file:139194-80-2.mol

Synonyms:139194-80-2;1-BROMO-3-(BROMOMETHYL)-5-NITROBENZENE;3-Bromo-5-nitrobenzyl bromide;Benzene, 1-bromo-3-(bromomethyl)-5-nitro-;3-Bromo-5-(bromomethyl)nitrobenzene;MFCD11040230;3-Bromo-5-nitrobenzylbromide;SCHEMBL602087;DTXSID90564823;LUTXVMDOMLHNIX-UHFFFAOYSA-N;AKOS028114035;PS-9860;SY326728;CS-0445834;EN300-177324;G19436;A1-00916

Suppliers and Price of 1-Bromo-3-(bromomethyl)-5-nitrobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-Bromo-3-(bromomethyl)-5-nitrobenzene
50mg
$ 110.00

SynQuest Laboratories
3-Bromo-5-nitrobenzyl bromide
250 mg
$ 128.00

SynQuest Laboratories
3-Bromo-5-nitrobenzyl bromide
1 g
$ 320.00

SynQuest Laboratories
3-Bromo-5-nitrobenzyl bromide
5 g
$ 960.00

Labseeker
1-BROMO-3-(BROMOMETHYL)-5-NITROBENZENE 95
25g
$ 1867.00

Crysdot
3-Bromo-5-nitrobenzylbromide 96%
1g
$ 450.00

Apolloscientific
3-Bromo-5-nitrobenzylbromide
1g
$ 290.00

Apolloscientific
3-Bromo-5-nitrobenzylbromide
250mg
$ 116.00

Apolloscientific
3-Bromo-5-nitrobenzylbromide
5g
$ 870.00

American Custom Chemicals Corporation
1-BROMO-3-(BROMOMETHYL)-5-NITROBENZENE 95.00%
5MG
$ 502.46

Total 2 raw suppliers

Chemical Property of 1-Bromo-3-(bromomethyl)-5-nitrobenzene

Chemical Property:

PSA：45.82000
LogP:3.77540
XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:294.86665
Heavy Atom Count:12
Complexity:171

Purity/Quality:

99.0%min ^*data from raw suppliers

1-Bromo-3-(bromomethyl)-5-nitrobenzene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=C(C=C(C=C1[N+](=O)[O-])Br)CBr

Technology Process of 1-Bromo-3-(bromomethyl)-5-nitrobenzene

There total 4 articles about 1-Bromo-3-(bromomethyl)-5-nitrobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 139194-79-9
(3-bromo-5-nitrophenyl)methanol

: 139194-80-2
1-bromo-3-(bromomethyl)-5-nitrobenzene

Guidance literature:: With N-Bromosuccinimide; triphenylphosphine; In tetrahydrofuran; at 0 - 20 ℃; for 16h;

Reference yield:

: 52488-28-5
1-bromo-3-methyl-5-nitrobenzene

: 139194-80-2
1-bromo-3-(bromomethyl)-5-nitrobenzene

Guidance literature:: With N-Bromosuccinimide; dibenzoyl peroxide; In pyrographite;

Reference yield:

: 89-62-3
4-methyl-2-nitroaniline

: 139194-80-2
1-bromo-3-(bromomethyl)-5-nitrobenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: hydrogen bromide; sodium chlorate / water; acetic acid / 5 - 45 °C

2.1: sodium nitrite; hydrogenchloride / water; acetic acid / 2 h / 5 - 10 °C

2.2: 48 h / 0 - 20 °C

3.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 16 h / Reflux

With hydrogenchloride; sodium chlorate; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); hydrogen bromide; sodium nitrite; In tetrachloromethane; water; acetic acid;
DOI:10.1016/j.bmcl.2016.09.075