PhCH₂Co(dmgH)(dpgH)(H₂O)

Base Information

• Chemical Name: PhCH₂Co(dmgH)(dpgH)(H₂O)
• CAS No.: 866632-04-4
• Molecular Formula: C₂₅H₂₇CoN₄O₅
• Molecular Weight: 522.506
• Mol file: 866632-04-4.mol

Synonyms:

Chemical Property of PhCH₂Co(dmgH)(dpgH)(H₂O)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PhCH₂Co(dmgH)(dpgH)(H₂O)

There total 1 articles about PhCH₂Co(dmgH)(dpgH)(H₂O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

PhCH2Co(dmgH)(dpgH)(Py) (281669-15-6) + water (7732-18-5) → PhCH2Co(dmgH)(dpgH)(H2O) (866632-04-4)

Guidance literature:

In methanol; acetone; Co-contg. compd. (0.260 mmol) and Dowex 50WX8-100 ion-exchnge resin weremixed together with stirring in acetone:methanol (1:1) mixt.; water was added; stirring for 17 h at 25°C (color changed from light to da rk orange); Dowex was filtered off and the vol. was reduced by rotary-vac. evaporator; the soln. contg. solid ppt. was kept for 1 h in refrigerator;

DOI:10.1016/j.jorganchem.2005.05.021

Reference yield: 70.0%

1,4-pyrazine (290-37-9) + PhCH2Co(dmgH)(dpgH)(H2O) (866632-04-4) → [PhCH2Co(dmgH)(dpgH)]2-μ-pyrazine (866632-02-2)

Guidance literature:

In methanol; acetone; under N2; pyrazine (0.100 mmol) in acetone was added to a soln. of Co-contg. compd. (0.200 mmol) in acetone:methanol (1:1) mixt.; the react. mixt. was stirred for 2 hin diffused light; TLC on silica gel (CH2Cl2); the soln. was concd. by evapn. of the solvent and diethyl ether was added; the ppt. was filtered, washed with diethyl ether and dried over P2O5 under vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2005.05.021

upstream raw materials:

PhCH₂Co(dmgH)(dpgH)(Py)

water

Downstream raw materials:

[PhCH2Co(dmgH)(dpgH)]2-μ-pyrazine