fac-Mo(N₂)(triphos)(dmpm)

Base Information

Chemical Name:fac-Mo(N₂)(triphos)(dmpm)
CAS No.:97550-91-9
Molecular Formula:C₃₉H₄₇MoN₂P₅
Molecular Weight:794.624
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of fac-Mo(N₂)(triphos)(dmpm)

Chemical Property:

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Technology Process of fac-Mo(N₂)(triphos)(dmpm)

There total 2 articles about fac-Mo(N₂)(triphos)(dmpm) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 75365-55-8,97590-53-9,178457-45-9
MoCl₃(triphos)

: 64065-08-3
dmpm

: 115510-63-9,97550-91-9
fac-Mo(N₂)(triphos)(dmpm)

Guidance literature:: With sodium amalgam; nitrogen; In tetrahydrofuran; react. in a rapidly sealed pressure bottle, stirring 5h at 0 °C and 12 h at ambient temp. under N2 (75 psi), transference to a glovebag; filtration, N2 through the filtrate (dark red filtrate), addn. of CH3OH, N2 through the soln. pptn. (bright orange solid), solid dried in vac. for 15 h, recrystn. (heptane, toluene), elem. anal.;

Reference yield:

: 75365-55-8,97590-53-9,178457-45-9
MoCl₃(triphos)

: 64065-08-3
dmpm

: 115481-62-4
Mo(triphos)(dmpm)(η1-dmpm)

: 115510-63-9,97550-91-9
fac-Mo(N₂)(triphos)(dmpm)

Guidance literature:: With sodium amalgam; nitrogen; In tetrahydrofuran; react. in a rapidly sealed pressure bottle, stirring 5h at 0 °C and 12 h at ambient temp. under N2 and Ar (75 psi), transference to a glovebag; filtration, addn. of CH3OH, pptn., purple solid washed and dried in vac., recrystn. (toluene, methanol);

Reference yield: 74.0%

: 115510-63-9,97550-91-9
fac-Mo(N₂)(triphos)(dmpm)

: fac-{Ni(N₂H₂)(PhP(CH₂CH₂PPh₂)2)(Me₂PCH₂PMe₂)}(CF₃SO₃)2

Guidance literature:: With triflic acid; In tetrahydrofuran; all manipulations under N2 or vac.; adding dropwise triflic acid to a stirred soln. of the complex (-78°C), pptg. and color changing to green within 0.25 h, standing (2 h, -78°C); filtering, washing (pentane), drying; elem. anal.;