N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine

Base Information

• Chemical Name: N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine
• CAS No.: 755019-11-5
• Molecular Formula: C₃₃H₅₀N₂O₃
• Molecular Weight: 522.772
• Mol file: 755019-11-5.mol

Synonyms:

Chemical Property of N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine

There total 1 articles about N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5-di-tert-butyl-2-hydroxybenzaldehyde (37942-07-7) + 1,3-Diamino-2-hydroxypropane (616-29-5) → N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine (755019-11-5)

Guidance literature:

In ethanol;

DOI:10.1246/bcsj.79.1393

Reference yield: 93.0%

N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine (755019-11-5) + bis(acetylacetonate)oxovanadium (3153-26-2) + cerium(III) acetylacetonate monohydrate + acetonitrile (75-05-8,26809-02-9) → [(V(V)O2(N,N'-bis-3,5-di-tert-butylsalicylidene-2-hydroxy-1,3-propanediamine(-3H)))2Ce(IV)]*4(acetonitrile)

Guidance literature:

With air; In acetonitrile; ligand, V compd. and Ce compd. (molar ratio 2:2:1) added to MeCN; stirred in air at 70°C for 3 h; filtered; filtrate evapd. to dryness; recrystd. from MeCN in air; elem. anal.;

DOI:10.1246/bcsj.79.1393

Reference yield: 45.0%

N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine (755019-11-5) + copper(II) perchlorate hexahydrate + Bis(p-nitrophenyl) phosphate (645-15-8) + acetonitrile (75-05-8,26809-02-9) → [Cu2(N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine(-3H))(bis(4-nitrophenyl)phosphate)]*3MeCN

Guidance literature:

With Et₃N; In N,N-dimethyl-formamide; acetonitrile; ligand and Et3N in MeCN-DMF added to MeCN soln. of Cu salt; stirred at room temp. for 1 h; phosphate and Et3N in MeCN added; stirred for 3 h; filtered; crystd. by slow evapn. of filtrate for several mo; filtered; crystals washed with Et2O; dried in air; elem. anal.;

DOI:10.1039/b819052f

upstream raw materials:

3,5-di-tert-butyl-2-hydroxybenzaldehyde

1,3-Diamino-2-hydroxypropane

Downstream raw materials:

[Cu₂(N,N'-bis(3,5-di-tert-butylsalicylidene-2-hydroxy)-1,3-propan-2-ol-diamine(-3H))(benzoate)]*DMF