(2S)-1-(3-mesitylpropanoyl)-2-methylazepane

Base Information

Chemical Name:(2S)-1-(3-mesitylpropanoyl)-2-methylazepane
CAS No.:1346682-02-7
Molecular Formula:C₁₉H₂₉NO
Molecular Weight:287.445
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S)-1-(3-mesitylpropanoyl)-2-methylazepane

Chemical Property:

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Technology Process of (2S)-1-(3-mesitylpropanoyl)-2-methylazepane

There total 2 articles about (2S)-1-(3-mesitylpropanoyl)-2-methylazepane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7496-99-3
(±)-2-methyl-azepane

: C₁₅H₂₀O₂

: (2R)-1-(3-mesitylpropanoyl)-2-methylazepane

: 1346682-02-7
(2S)-1-(3-mesitylpropanoyl)-2-methylazepane

: C₇H₁₅N

: 2-(R)-methylhexahydroazepine

Guidance literature:: With 2-(2,4,6-trimethyl-phenyl)-2,5,6,7-tetrahydro-pyrrolo[2,1-c] [1,2,4]triazol-4-ylium perchlorate; (4aR,9aS)-6-bromo-4-hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one; potassium carbonate; In Isopropyl acetate; at 23 ℃; for 24h; Resolution of racemate;
DOI:10.1039/c2cc34907h

Reference yield:

: 7496-99-3
(±)-2-methyl-azepane

: 1346681-71-7
(1E)-4-hydroxy-1-mesityl-4-methylpent-1-en-3-one

: 501-53-1,94274-21-2
benzyl chloroformate

: 1346682-01-6
benzyl (2R)-2-methylazepane-1-carboxylate

: benzyl (2S)-2-methylazepane-1-carboxylate

: (2R)-1-(3-mesitylpropanoyl)-2-methylazepane

: 1346682-02-7
(2S)-1-(3-mesitylpropanoyl)-2-methylazepane

Guidance literature:: (±)-2-methyl-azepane; (1E)-4-hydroxy-1-mesityl-4-methylpent-1-en-3-one; With 2-(2,4,6-trimethyl-phenyl)-2,5,6,7-tetrahydro-pyrrolo[2,1-c] [1,2,4]triazol-4-ylium perchlorate; (4aR,9aS)-4-hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 23 ℃; for 18h; Inert atmosphere;

benzyl chloroformate; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 2h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja209472h